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Octahedron symmetry

Fig. 3.8 The tetrahedron T symmetry), octahedron (Oh S5mmetry) and icosahedron (7h symmetry) possess four, six and twelve vertices respectively, and four, eight and twenty equilateral-triangular faces respectively. Fig. 3.8 The tetrahedron T symmetry), octahedron (Oh S5mmetry) and icosahedron (7h symmetry) possess four, six and twelve vertices respectively, and four, eight and twenty equilateral-triangular faces respectively.
Symmetry of orbitals on the B6 octahedron, (a) Six outward-pointing (sp) orbitals used for a bonding to 6 H. (b) Six inward-pointing (sp) orbitals used to form the fi framework bonding molecular orbital, (c) ComponenLS for one of the fiM framework bonding molecular orbitals — the other two molecular orbitals are in the yz and zr planes, (d) (Components ftM one of the t2 framework bonding molecular orbitals — the other two molecular orbitals are in the yz and x planes. [Pg.177]

Octahedral Having the symmetry of a regular octahedron. In an octahedral species, a central atom is surrounded by six other atoms, one above, one below, and four at the comers of a square, 176 complex in transitional metals, 418-420 geometric isomerism, 415 Octane number, 584... [Pg.693]

The compounds of the MMe205F type, where Me = Nb or Ta M = Rb, Cs, Tl, crystallize in cubic symmetry and correspond to a pyrochlore-type structure [235-237]. This structure can be obtained from a fluorite structure by replacing half of the calcium-containing cubic polyhedrons with oxyfluoride octahedrons. [Pg.101]

The left superscript indicates that the arrangements are all spin triplets. The letter T refers to the three-fold degeneracy just discussed and it is in upper case because the symbol pertains to a many-electron (here two) wavefunction (we use lower-case letters for one-electron wavefunctions or orbitals, remember). The subscript g means the wavefunctions are even under inversion through the centre of symmetry possessed by the octahedron (since each d orbital is of g symmetry, so also is any product of them), and the right subscript 1 describes other symmetry properties we need not discuss here. More will be said about such term symbols in the next two sections. [Pg.37]

We shall shortly draw on both of these symmetry and energy aspects of Fig. 6-1 in the construction of molecular orbitals for the octahedron. First, however, let us extend the picture to molecules with more than two atoms. [Pg.103]

Hexaborides of a CaBg type are formed by K, the alkaline earths, Y and the larger lanthanides, as well as Th and some actinides ". The crystal structure of these compounds with cubic symmetry (Pm3m, O, ) (see Fig. 1) is characterized by a three-dimensional skeleton of Bg boron octahedra, the interstices of which are filled by metal atoms. The connection between two octahedra is by a B—B bond of length 1.66 X 10 pm, whereas the B—B bond lengths in one octahedron are 1.76 X 10 pm. ... [Pg.222]

Th = symmetry of an octahedron without fourfold axes [2/m3, short m3 ]. [Pg.20]

You say that your nonlinear molecule has the high symmetiy of a regular polyhedron, such as a tetrahedron, cube, octahedron, dodecahedron, icosahedron,... sphere. If it is a sphere, it is monatomic. On the other hand, if it is not monatomic, it has the symmetry of one of the Platonic solids (see the introduction to Chapter 8). [Pg.191]


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See also in sourсe #XX -- [ Pg.1323 ]




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Octahedron

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