Suzuki-Miyaura, Ullmann, Sonogashira, and Heck Coupling Reactions

Suzuki-Miyaura, Ullmann, Sonogashira, and Heck Coupling Reactions 

The Pd/MIL-101 was found to catalyze the water-mediated Suzuki-Miyaura and Ullmann couphngs of aryl chlorides with isolated yield up to 98% using 0.5 mol% of Pd. The MOF-supported palladium nanoparticles were stable under several catalytic 

Following a similar methodology, Gao et al. [101] reported an MOF-based heterogeneous catalyst that consists of highly dispersed palladium nanoparticles 

Applications in Oxidation, Carbon-Oxygen, and Carbon-Nitrogen Bond Formation 

A Pd-MOF reported by Corma [60] was also found to be active in the partial oxidation of alcohols using air to oxidize 3-phenyl-2-propen-l-ol (cinnamyl alcohol). Ciimamyl alcohol is a suitable substrate to probe the activity and chemoselectivity of a catalyst for the aerobic alcohol oxidation. With Pd-MOF as catalyst and ambient pressure air as the oxidant, total conversion of ciimamyl alcohol was observed after 

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