Suzuki experimental procedures

Experimental Procedure 5.2 Suzuki couplinu with a polwvrene-hound arvl bromide [185]... 

Figure 3.6. The experimental procedure for the dissociation of the radical CH3CO. [Reprinted with permission from T. Shibata, H. Lai, H. Katayanagi, and T. Suzuki, J. Phys. Chem., A102 (1998), p. 3643. Copyright 1998, American Chemical Society.]...

Three principal types of Suzuki polymerizations for polyfluorenes have been developed for homopolymers and copolymers by Dow, Cambridge Display Technology (CDT), and Covion, which was merged with Merck. Early detailed experimental procedures were reported in the patent literature (Scheme 5.5 and Table 5.2). These and other groups have used these polymerizations for numerous poly fluorene derivatives (Table 5.3). 

In addition, chiral diene-palladium complexes (Experimental Procedure below, adapted from ref. ) offer the possibility for asymmetric reactions, such as asymmetric Suzuki coupling reactions. 

Coupling partner for Suzuki reaction can be boronic acids, their esters, trifluoroborates, or boranes (in particular derived from 9-borabicyclononane (9-BBN) jV-methylimino diacetic acid (MIDA) boronates (Scheme 5-57) developed by Burke pose a very useful alternative to boronic acids, as they are stable under some different palladium-catalysis e.g., Stille couplings) and can be "switched on" by nucleophiles. An application is shown in the following Experimental Procedure. ... 

Suzuki coupling reactions can be combined with an iridium-catalyzed CH-activation using pinacolborane (Experimental Procedure below). ... 

As noted in the paragraph dealing with diazonium salts in the Heck reaction, diazonium salts are versatile starting materials for cross-coupling reactions. Recently, Schmidt and co-workers used the Suzuki coupling in the presence of diazonium salts (Experimental Procedure below). 

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