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Sulfoxide, dibenzyl Pummerer rearrangement

The Pummerer rearrangement was reported by Rudolf Pummerer in 1909 when he published a paper in Chemische Berichte. Earlier in the same year, Smythe had reported the reaction of dibenzyl sulfoxide 3 with acetic anhydride and hydrochloric acid to give benzaldehyde 4 and thioacetal 5, among other products. Smythe was apparently unable to explain the product distribution, which was then left to Pummerer do so in his much-cited paper later that year. Pummerer published the reaction of sulfinyl acetic acid 6 with hydrochloric acid to give glyoxylic acid 7. The formal oxidation of the... [Pg.334]

See other pages where Sulfoxide, dibenzyl Pummerer rearrangement is mentioned: [Pg.194]    [Pg.194]   
See also in sourсe #XX -- [ Pg.194 ]

See also in sourсe #XX -- [ Pg.194 ]

See also in sourсe #XX -- [ Pg.7 , Pg.194 ]

See also in sourсe #XX -- [ Pg.7 , Pg.194 ]

See also in sourсe #XX -- [ Pg.194 ]



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Dibenzyl sulfoxide

PUMMERER Sulfoxide rearrangement

Pummerer

Pummerer rearrangement

Rearrangement sulfoxide

Sulfoxides rearrangement

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