Sulfonimidoyl-Substituted Mono allyl titanium Complexes

We were particularly interested to see whether a regio- and stereoselective hy-droxyalkylation and amrnoalkylation of 1 and 2 with aldehydes and imino esters, perhaps by choice of the substituent X at the Ti atom, with formation of the corresponding sulfonimidoyl-substituted homoallyl alcohols 4-7 and the homoallyl amines 8-11 (Fig. 1.3.3) could be achieved. Reggelin et al. had already demonstrated that the sulfonimidoyl-substituted mono(allyl)titanium complexes 3, the... 

Scheme 1.3.7 Synthesis of chiral sulfonimidoyl-substituted mono(allyl)titanium complexes.

Sulfonimidoyl-Substituted Mono(allyl)tris(diethylamino)titanium Complexes... 

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