Sulfides reaction with peroxy acids

LEAD MONOXIDE (1317-36-8) A strong oxidizer. Explosive reaction with 90% peroxy-formic acid, rubidium acetylide. Reacts violently with strong oxidizers, boron, chlorine, fluorine, dichloromethylsilane, calcium sulfide, hydrogen peroxide, hydrogen trisulfide (ignition), hydroxylamine (ignition), lithium carbide, metal acetylides, metal powders (e.g., aluminum, molybdenum, zirconium, etc.), perchloric acid, red phosphorus, selenium oxychloride, sodium. Incompatible with aluminum carbide, barium sulfide, silicon, sulfuryl chloride. Forms impact-sensitive explosive mixtures with dichloromethylsilane. May attack plastics, coatings, and chlorinated rubber materials such as Hypalon , Parlon , Rutile , and fluorinated rubbers such as Viton . 

Ozonation of Heteroatoms. Phosphines are converted to phosphine oxides and phosphites to phosphates by ozone. These reactions are quite general and a wide range of sub-stitutents can be tolerated. Phosphine oxides also can be produced by the ozonation of alkylidenetriphenylphosphoranes or of thio- or selenophosphoranes. Organic sulfides are converted to sulfoxides and sulfones by ozonation. Tertiary amines are converted to amine oxides, while nitro compounds can be produced in modest yields by ozonation of primary amines. This preparation of nitroalkanes compares well with alternate approaches using peroxides, peroxy acids, permanganate, or Monoperoxysulfuric Acid, but ozonation on silica gel has proven to be superior (see Ozone-Silica Get). Selenides are converted to selenoxides by ozone and this reaction is often used to achieve overall production of unsaturated carbonyl compounds. An example is shown in eq 25. ... 

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