Sulfato complexes stability

U1 "1" (16), and Np1 "1" (17) (Table IV). Only in the thorium system have stability constants been determined as a function of acidity. Zebroski et al., (12) found that the 1 2 complex had the form TMSOi, at 0.5 M and 1.0 M acidity but suggested a contribution from the monoprotonated, bis-sulfato complex in 2 M acid. However, Zielen (9) found no evidence for such a species. The Kj/K2 ratio found in the latter study (n.8) compares favorably with the Am(III)-S0 data of DeCarvalho and Choppin (10)... 

As was observed in the case of the extraction of zirconium and hafnium from nitrate media, it is probable that the different tendencies of the metals towards hydrolysis has some effect on the selectivity observed,298 313 expecially in view of the proved extraction of hydroxo complexes. The extraction of both metals decreases markedly in the presence of sulfate ions in the aqueous phase (a feature that is utilized in the stripping of the loaded hafnium with sulfuric acid), although the selectivity for hafnium over zirconium is simultaneously increased on account of the higher stability constants of the inextractable sulfato complexes of zirconium.298... 

Because mercury forms relatively stable hydroxo, sulfato, and chloro complexes in solution, the solubilities and relative stabilities of mercury minerals depend heavily on ambient solution compositions. Figure 4 illustrates the calculated effect of pH and total sulfate on the solubility of schuetteite. The curves take into account all complexes for which data are available in Martell and Smith (18) and precipitation of HgO they cross when changes in solution composition result in changes in dominance among complexes. Schuetteite is quite soluble relative to HgS and elemental mercury under common conditions. 

The presence of vanadium(III) complexes in the very acidic medium of the vacuoles of the signet ring cells in Ascidia ceratodes, containing one or two sulfato/hydrogensulfato ligands, has focused interest on sulfatovanadium complexes as model systems. " ] Whereas readily forms a 1 1 complex with sulfate K = 300 m ), the affinity of V to sulfate is less pronounced. Selected stability constants and pA a values obtained from... 

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