Sublimation enthalpies transition metals

Values of the sublimation enthalpy of main group and transition metals are shown in Table 2.3 2... 

Sublimation enthalpies, energies of atoms in ideal kink positions and bond energies between the two nearest atoms, main group and transition metals ... 

Sublimation enthalpies calculated with the Bom-Haber cycle in Figure 2.39 for transition metals A in B... 

Bond energies calculated from the sublimation enthalpies for alloys of transition metals... 

Chemistry of the Heaviest Elements ) sufficiently accurate, predict —A// (F1) = 68 kJ mol somewhat less volatile than Cn [146]. It was argued, that on transition metal surfaces FI should adsorb stronger than Cn, due to chemical forces since the 7pi/2(Fl) atomic orbital is less stabilized than the 7i(Cn) atomic orbital. On the other hand, relativistic solid-state calculation yield cohesive energies (equivalent to sublimation enthalpies) which are higher for Cn (1.1 eV [138]) compared to FI (0.5 eV [147]). This prediction is at variance with the calculation from [146] under the assumption that sublimation enthalpies correlate with the adsorption enthalpies on Au surfaces see Fig. 38. 

Standard electrode potentials and stability of different oxidation states of transition metal ions in aqueous solutions The stability of a particular oxidation state in solution can be explained in terms of its electrode potential which in turn depends upon enthalpy of sublimation, ionization energy and hydration energy. 

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