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Stochastic kinetics, anomalous

In this paper the outlines of anomalous stochastic kinetic models are discussed. These models are derived by relaxing certain traditional assumptions. Furthermore, a very specific example is given to illustrate that spatial inhomogenity can lead to time inhomogenity by some lumping procedure. [Pg.511]

The occurence of deviance from the usual assumptions (i.e. ordered structure of time, space and energy) leads to anomalous stochastic kinetic models. [Pg.515]

For near and supercritical conditions, combustion gas-phase data are often used as the point of reference to assess solvent effects. The gas-phase values of kig, available for temperatures 800-2500 K, show the activation energy 90 kJ mol In condensed phase, stabilization of H2O molecules via H-bonding may increase the activation barrier, but on the other hand the reaction can be promoted by the solvent cage effect. Diffusion-kinetic modelling and stochastic simulation of chemical reactions in radiation tracks have shown that the occurrence of reaction (15.19) is consistent with the anomalous increase in H2 yield observed in water radiolysis at temperatures above 523 K, if kig is of the order of 1-2x10 s (4-8x10 s ) at 573 K. Considering the two... [Pg.393]


See other pages where Stochastic kinetics, anomalous is mentioned: [Pg.511]    [Pg.619]    [Pg.450]    [Pg.625]    [Pg.325]    [Pg.114]    [Pg.90]    [Pg.337]    [Pg.154]   
See also in sourсe #XX -- [ Pg.511 ]




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