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Stepwise and Overall Formation Constants for Complex Ions

Stepwise and Overall Formation Constants for Complex Ions [Pg.236]

The formation of Ni(CN) (Table 9-2) is typical in that it occurs in steps as shown. Note that stepwise formation constants are symbolized by K, K2, and so forth. [Pg.236]

Aqueous solutions contain small concentrations of hydronium and hydroxide ions as a consequence of the dissociation reaction [Pg.236]

An equilibrium constant for this reaction can be formulated as shown in Equation 9-7  [Pg.236]

The concentration of water in dilute aqueous solutions is enormous, however, when compared with the concentration of hydrogen and hydroxide ions. As a consequence, [H2OP in Equation 9-10 can be taken as constant, and we write [Pg.236]




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Complex formation constants for

Complex ion, formation

Complex ions formation constant

Complexes constants

Complexes overall formation constant

Complexes stepwise formation constant

Complexing constants

Complexity constant

Constants complexation, formation

Formate ion

Formation constant

Formation constant overall

Ion formation

Stepwise

Stepwise complex formation

Stepwise formation constant

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