Status and Future Developments

In the development of the discussed fluorinated products a lot of fundamental insight has been gained into permeation and adhesion properties of surface-fluorinated polymers. Although this insight is not discussed in this paper, it may be of interest to mention a few significant fundamental discoveries and also to suggest directions for future development. 

It may be possible to predict the permeation characteristics of the fluorinated layer by using the acid-base theory of surface energy together with solubility theory.  

The role of additives in plastics in the creation of low-permeability fluorinated layers is totally underestimated/ignored in the open literature. 

The conclusion that might be drawn from published results, that adhesive/coating systems adhere just as well to fluorinated and oxfluorinated surfaces, is not supported by our experience based on activation conditions normally encountered in commercial postfluorination plants. 

We have found enough exceptions to refrain from predicting that a specific adhesive system, e.g., epoxy or polyester, will always adhere better to a fluorinated or oxfluorinated surface. 

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