Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Static reactor liquid phase methods

Liquid Phase Methods Static and Rotating Reactors (3-7,10,12)... [Pg.170]

The iron vapor-toluene reaction has evoked interest because of the lability of the proposed bis(arene)iron complex to ligand subsitu-tion and to loss of both toluene molecules to free the metal atom. In the latter case the toluene molecules may be usefully regarded as metal atom carriers which can be used to direct the latent reactivity of the atom in subsequent solution phase chemistry. In this way the metal atom experiment can benefit from the convenience and additional versatility afforded by bench-top chemical manipulations. These results are relevant to a reported preparation of a dehydroxy-lated silica-supported Fischer-Tropsch catalyst from a static reactor codeposition of Fe and toluene.(46) In the liquid phase, iron atoms "bottled" in this way have also been utilized in an exceedingly mild method for making minute catalytically active superparamagnetic clusters on the surface and within the cavities of a dehydrated sodium zeolite Y.(38) Using the rotary reactor, preformed solutions of solvated iron atoms (as the toluene complex) are cannulated below their decomposition temperature out of the flask to a cold slurry of the support in toluene. Diffusion of intact... [Pg.178]


See other pages where Static reactor liquid phase methods is mentioned: [Pg.160]    [Pg.77]    [Pg.674]    [Pg.74]    [Pg.207]    [Pg.546]    [Pg.1313]   
See also in sourсe #XX -- [ Pg.170 ]




SEARCH



Liquid phase reactors

Liquid reactors

Liquid static

Method phase

Reactor Methods

Reactor phase

Reactor static

Static phase

Static, method

© 2024 chempedia.info