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Starches ring conformations

This peak is attributed to starch ring vibrations [92, 120], and does not correspond to crystalline or gelatinized amylose but to a complexed one, which results when amylose assumes V-type structures conformations after destructurization. Comparable starch-based materials with an amylose content close to zero, even in presence of complexing agents, do not show any peak at 947 cm. ... [Pg.24]

In the cyclodextrins readily obtainable from starch, the six (a-CD), seven (P-CD) and eight (y-CD) a(l- 4)-linked glucose units are "locked up" in a strait-jacket type belt due to adoption of 4Cj chair conformations of the pyranoid rings and a net of 2-OH — OH-3 hydrogen bonds (73, 74). As this structural rigidity even persists on inclusion complex formation, as exemplified by the three represenatives in Fig. 1 (75 - 78) ... [Pg.71]


See other pages where Starches ring conformations is mentioned: [Pg.120]    [Pg.254]    [Pg.254]    [Pg.93]    [Pg.814]    [Pg.402]    [Pg.650]    [Pg.814]    [Pg.265]    [Pg.101]    [Pg.200]    [Pg.255]    [Pg.74]    [Pg.262]    [Pg.9]    [Pg.143]    [Pg.63]    [Pg.269]    [Pg.226]    [Pg.86]    [Pg.255]    [Pg.943]    [Pg.485]    [Pg.125]    [Pg.70]    [Pg.123]    [Pg.413]    [Pg.120]    [Pg.7804]    [Pg.232]    [Pg.294]    [Pg.123]    [Pg.143]    [Pg.149]   
See also in sourсe #XX -- [ Pg.254 ]




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Rings conformations

Starch conformation

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