SSITKA experiments transient kinetic analysis

In the present communication we report on the influence of water on the FT synthesis studied by SSITKA and conventional kinetic experiments. Steady-state isotopic transient kinetic analysis (SSITKA) has proved to be a powerful technique for this work. The technique involves switching between CO and " CO in the feed gas and analyzing the transients with respect to the formation of products containing C and C. This technique allows the determination of the true turnover frequency of the active site, decoupled from site coverage. Applied to the FTS over metal promoted cobalt catalysts SSITKA has shown that the true turnover frequency of cobalt always remains the same, regardless of the second metal [6-8]. 

Pulse intensities in vacuum experiments range from 10 to 10 molecules per pulse with a pulse width of 250 ps and a pulse frequency of between 0.1 and 50 pulses per second. Such a spectrum of time resolution is unique among kinetic methods. Possible experiments include high-speed pulsing, both single-pulse and multipulse response, steady-state isotopic transient kinetic analysis (SSITKA), temperature-programmed desorption (TPD), and temperature-programmed reaction (TPR). 

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