South American shelf

Figure 6 Schematic figure of the western South American shelf and slope, showing contours of dissolved phosphate and oxygen in the bottom waters and the locations of aerobic and anaerobic sediments, phosphorite and Recent phosphorite deposits. (After Burnett WC, Veeh HH and Soutar A (1980) U-series, oceanographic and sedimentary evidence in support of recent formation of phosphate nodules off Peru. In Marine Phosphorites, SEPM Special Publ. no. 29, pp. 61-72.)...

How can this enigma be answered Put away a sample of pure harmaline, with its spectral identification, onto the shelf for 50 or 100 years, and then re-analyze it Who knows, but what might be needed for this conversion is heat, or a bit of iron catalyst, or some unknown species of South American mold. Acid is certainly known to promote this oxidation. It would be very much worth while to answer this question because some, perhaps much, of the results of human pharmacological studies that involve harmaline as a metabolic poison, may be influenced by the independent action of harmine as a harmaline contaminant. 

Phosphorites (manne apatites) are dense, hght-brown-to-black concretions, ranging in size from sands to nodules and irregular masses. Phosphorites have been found off Argentina, Chile, Japan, Mexico, Peru, South Africa, and Spain, and several islands in the Indian Ocean. Some also have been found off the west coast of North America and on the eastern North American continental shelf These deposits occur where water upwelling transports phosphorus and where the rate of sedimentation is slow. The... 

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