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Solvolysis by Ammonia and Amines

Pentamethylchlorodisilane reacts with ammonia to bis-(pentamethyldisilanyl)-amine404  [Pg.35]

Si2Cl6, too, certainly reacts with amines. With secondary amines, not only is the hexasubstituted compound obtained but partially substituted compounds can also be isolated. [Pg.35]

In a side reaction, nucleophilic Si—Si cleavage sometimes takes place52  [Pg.35]

Si2Cl6 + 7 HNet2 — Cl2Si(Net2)2 + ClHSi(Net2)2 + 3 HNet2 HC1. [Pg.35]

Reactions with organofunctional disilanes are also known362)  [Pg.36]


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Amines ammonia

Amines by amination

Ammonia and amines

And solvolysis

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