Sodium bromate NaBrO

Oxidation. Oxidation of the -amyl alcohols produces aldehydes, which after continued oxidation can yield acids. This route to aldehydes has httle merit. However, oxidative esterifications with alkah metal hypohaUtes (eg, calcium chlorite, Ca(OCl)2) (49), bromates (eg, sodium bromate, NaBrO )... [Pg.373]

Sodium bromate, NaBrOs.—The bromate is formed by the action of bromine on a hot solution of sodium hydroxide, but is best obtained by the electrolysis of sodium bromide under certain conditions. [Pg.105]

Sodium bromate, NaBrOs, a white crystalline compound, converts acyloins into a-diketones under forcing conditions [740]. More often, this reagent is used as a reoxidant of ammonium cerium nitrate [421], cerium sulfate [741], or ruthenium trichloride [741] in oxidations of alcohols to aldehydes [421] or carboxylic acids [741]. [Pg.29]

Sodium bromate, NaBrOs. See Figure 11.22fo. Note the bands at 447... [Pg.327]

The stability of the halate(I) ion decreases, as expected, from C10 to 10 and only the chlorate(I) ion can be considered reasonably stable even in aqueous solution. Solid sodium bromate(I). NaBrO (with five or seven molecules of water of crystallisation) can be obtained, but on standing or warming it disproportionates ... [Pg.338]

NaBrOs SODIUM BROMATE Molecular weight 150.892 System cubic a 0.6705 Density Z 4 3325... [Pg.203]

Another method involves adding excess bromine to a solution of sodium hydroxide. This forms sodium bromide andbromate. The product solution is evap-oated to dryness. The bromate is reduced to bromide by heating with carbon 3Br2 + 2NaOH + H2O NaBr + NaBrOs -1- 4HBr... [Pg.860]

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