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Sodium azide reaction with trialkylboranes

Iron(n) salts mediated the coupling of trialkylboranes with KSGN to give RSCN via a radical process.553,554 Stereochemically pure ( )-l-thiocyanato-alkenes or ( )-l-azide-alkenes were obtained from alkynes when hydro-boration with disiamylborane was followed by reaction with potassium thiocyanate or sodium azide in the presence of copper(n) nitrate, copper(n) acetate, and small amount of water in polar aprotic solvent (Equation (116)).555... [Pg.190]


See also in sourсe #XX -- [ Pg.607 ]

See also in sourсe #XX -- [ Pg.607 ]

See also in sourсe #XX -- [ Pg.7 , Pg.607 ]

See also in sourсe #XX -- [ Pg.7 , Pg.607 ]

See also in sourсe #XX -- [ Pg.607 ]




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Azidation reaction

Azides, reactions

Azides, sodium with

Reaction with azide

Reaction with sodium azide

Sodium azide

Sodium azide, reaction with azides

Sodium reaction with

Trialkylborane

Trialkylboranes

Trialkylboranes reactions

With Azides

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