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Small Caged Molecules ligand

Small pores measurements of pore size distributions revealed that from all supports studied, only Merck 40 has a considerable portion of small pores (about 50% of the surface is in pores with a size < 4nm). Possibly, the lower selectivity (ee 86.8-89.8%) obtained with this support may be a consequence of tight caging of immobilized cateilyst molecules. The lower activity observed with high loading (ligand Im) indicates that a dense coating of small pores with ligand molecules can reduce or even block mass transport. [Pg.112]


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Cage molecules

Ligand molecules

Ligand small molecule

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