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Skeletal structures with charged carbon atoms

C Skeletal Structures with Charged Carbon Atoms... [Pg.31]

Pentadienyl carbanions are analogous to allyl anions with an extended delocalization of charge. Reaction of 1,3- or 1,4-pentadienes and alkali metals in THF in the presence of a base, such as NMes or TMEDA, affords crystalline pentadienylalkali metal complexes. A contact ion pair structure is predicted for these compounds by theoretical calculations and is consistent with solution structural data obtained by NMR. The pentadienyl anion usually interacts with the cation as an rj - or ) -ligand depending on the structural orientation of the backbone carbon atoms of the pentadienyl anion (W-, S-, or U-shaped skeletal structures). A contact ion pair structure having a W-shaped pentadienyl ligand is shown (16). 2,4-Disubstituted... [Pg.90]


See other pages where Skeletal structures with charged carbon atoms is mentioned: [Pg.105]    [Pg.1405]    [Pg.1405]    [Pg.2]    [Pg.33]    [Pg.165]    [Pg.184]    [Pg.343]    [Pg.661]    [Pg.130]    [Pg.520]    [Pg.170]    [Pg.519]   
See also in sourсe #XX -- [ Pg.31 ]




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Atomic charge

Atoms/atomic charges

Carbon charge

Carbon structure

Carbon structures with

Carbonate structure

Charge structural

Charged atoms

Charges atom

Skeletal atom

Skeletal carbonates

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