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Single-molecule conductance measurements

Chen IWP, Fu M-D, Tseng W-H, Chen C-h, Chou C-M, Luh T-Y (2007) The effect of molecular conformation on single molecule conductance measurements of 7i-conjugated oligoaryls by STM break junction. Chem Commun 29 3074—3076... [Pg.32]

Therefore, single molecule conductance measurements provide experimental evidence for theoretically expected behavior which cannot be determined by any other means but single molecule analysis. [Pg.128]

Ultimately electronics will consist of networks of molecules. Single molecule conductivity measurement was first done by using a scaiming tunneling microscope (STM) tip positioned above a molecule adsorbed to a metallic or semi-conducting surface [10] (Figures 10,11). [Pg.151]

A natural extension of the STM break junction technique was to perform analogous experiments using an EC-STM setup, allowing conductance measurements and single molecule trapping in electrolyte solutions. Haiss et al. were the first to accomplish this with their 2003 report on single molecule conductance measurements in a phosphate buffer solution for a 4,4 - bipyridinium derivative... [Pg.733]

Jang, S.-Y. Reddy, R Majumdar, A. Segalman, R. A. 2006. Interpretation of stochastic events in single molecule conductance measurements. Nano Lett. 2006 2362-2367. [Pg.747]

Cui XD, Primak A, Zarate X, Tomfohr J, Sankey OF, Moore AL, Moore TA, Gust D, Harris G, Lindsay SM (2001) Reproducible measurement of single-molecule conductivity. Science 294... [Pg.31]

Haiss W, Nichols RJ, van Zalinge H, Higgins SJ, Bethell D, Schiffrin DJ (2004) Measurement of single molecule conductivity using the spontaneous formation of molecular wires. PCCP 6(17) 4330-4337... [Pg.32]

Moore AM, Mantooth BA, Dameron AA, Donhauser ZJ, Lewis PA, Smith RK, Fuchs DJ, Weiss PS (2008) Measurements and mechanisms of single-molecule conductance switching. In Hasegawa M, Inoue A, Kobayashi N, Sakurai T, Wille L (eds) Frontiers in materials research. Advances in Materials Research, vol 10. Springer, Berlin, pp 29 -7... [Pg.36]

Xiao X, Xu B, Tao NJ (2004) Measurement of single molecule conductance benzenedithiol and benzenedimethanethiol. Nano Lett 4 267-271... [Pg.81]

Chen F, Hihath J, Huang ZF, Li XL, Tao NJ (2007) Measurement of single-molecule conductance. Amur Rev Phys Chem 58 535-564... [Pg.112]

He J, Sankey O, Lee M, Tao N, Li X, Lindsay S (2006) Measuring single molecule conductance with break junctions. Faraday Discuss 131 145-154... [Pg.112]

Figure 7-20. An illustration of the conducting AFM developed by Cui et al. for measuring single molecule conductance. Figure 7-20. An illustration of the conducting AFM developed by Cui et al. for measuring single molecule conductance.
The conducting AFM method has revealed interesting details of the single molecule conductance of carotene molecules. The electronic properties of carotenoids are of interest since they play a role in their biological function, especially their optical properties which are a manifestation of their delocalised electron structure. The structure of the dithiolated carotenoid used in a study by Ramachandran et al. is shown in Fig. 7-21. A synthetic molecular wire 2,5-di(phenylethynyl-4 -thioacetyl)benzene, also appraised by conducting AFM is also shown in Fig. 7-21. The measured low bias resistance of the carotenoid molecule was found to be (4.9 0.2) GQ. After... [Pg.230]

Haiss et al. have also demonstrated how single molecule conductance can be measured in electrolyte solution as a function of electrode potential. " This offers the ability to perform more defined measurements of single... [Pg.234]

Figure 7-25. Measurements of the single molecule conductance of 6V6 molecular wires performed under electrochemical control in 0.1 M phosphate buffer solution. The electrode potential dependence of the conductance at constant tip-sample bias (Ut = 0.2 V) of a single 6V6 molecule is shown. " ... Figure 7-25. Measurements of the single molecule conductance of 6V6 molecular wires performed under electrochemical control in 0.1 M phosphate buffer solution. The electrode potential dependence of the conductance at constant tip-sample bias (Ut = 0.2 V) of a single 6V6 molecule is shown. " ...
Chen, R, Hihath, J., Huang, Z.R et al. (2007) Measurement of single-molecule conductance. Annual Review of Physical Chemistry, 58, 535-564. [Pg.180]

Rod-type oligomers oligo(p-phenylene-ethynylene) and oligo(/7-phenylene-vinylidene), 71 and 73, respectively, with sulfur units at each end to provide alligator clips for the measurement of their single-molecule conductance through... [Pg.168]


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See also in sourсe #XX -- [ Pg.340 ]




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Conductance measurements

Conductance measurment

Conductance/conduction singles

Conducting molecules

Conduction measurements

Conductivity measurements

Measurements single molecule

Single measurements

Single-molecule conductance

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