Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Similarity solution Brownian

Hence, we use the trajectory that was obtained by numerical means to estimate the accuracy of the solution. Of course, the smaller the time step is, the smaller is the variance, and the probability distribution of errors becomes narrower and concentrates around zero. Note also that the Jacobian of transformation from e to must be such that log[J] is independent of X at the limit of e — 0. Similarly to the discussion on the Brownian particle we consider the Ito Calculus [10-12] by a specific choice of the discrete time... [Pg.269]

For systems that exhibit slow anomalous transport, the incorporation of external fields is in complete analogy to the existing Brownian framework which itself is included in the fractional formulation for the limit a —> 1 The FFPE (19) combines the linear competition of drift and diffusion of the classical Fokker-Planck equation with the prevalence of a new relaxation pattern. As we are going to show, also the solution methods for fractional equations are similar to the known methods from standard partial differential equations. However, the temporal behavior of systems ruled by fractional dynamics mirrors the self-similar nature of its nonlocal formulation, manifested in the Mittag-Leffler pattern dominating the system equilibration. [Pg.234]

It is assumed here that the temperature of the solution does not differ much from the Flory temperature Tp. Now, we recall that for d = 3, the three-body interaction is marginal, as can be seen from (14.6.2). Thus, for g 1 and d = 3, the situation of the system reminds us of the situation of the standard continuous model for d = 4, and these marginal systems will be treated in very similar manners (see Chapter 12, Section 3.3.4.2). This means that in practice, for g 4 1, the chains are nearly Brownian but that logarithmic corrections must be calculated. However, the fact that demixtion may occur when g is weakly negative introduces additional difficulties. [Pg.683]

Simpler BGK kinetic theory models have, however, been applied to the study of isomerization dynamics. The solutions to the kinetic equation have been carried out either by expansions in eigenfunctions of the BGK collision operator (these are similar in spirit to the discussion in Section IX.B) or by stochastic simulation of the kinetic equation. The stochastic trajectory simulation of the BGK kinetic equation involves the calculation of the trajectories of an ensemble of particles as in the Brownian dynamics method described earlier. [Pg.161]

The best way to attach the catalytic film to the porcelain was indicated by Professor Einstein s claim that According to the molecular kinetic theory, in a colloidal solution, there is no difference between a suspended particle and a molecule. Previous to this claim. Professor Jean Perrin, in his admirable study of the Brownian movement, had come to a qualified conclusion of similar nature. [Pg.505]

It remains, therefore, to seek such a method of finding the kinetic energy of a particle accessible to observation in the ultra-microscope while it is executing the Brownian motion. There are several such methods. The simplest depends upon a study of the sedimentation equilibrium. Particles heavier than the solution in which they are suspended would if at rest sink to the bottom. Their motion, however, keeps them suspended, though more thickly in the lower layers of the medium than in the higher ones. This sedimentation equilibrium is analogous to the equilibrium of the Earth s atmosphere under gravity and may be similarly treated. [Pg.17]


See other pages where Similarity solution Brownian is mentioned: [Pg.252]    [Pg.170]    [Pg.211]    [Pg.420]    [Pg.561]    [Pg.190]    [Pg.239]    [Pg.294]    [Pg.228]    [Pg.396]    [Pg.22]    [Pg.238]    [Pg.245]    [Pg.2]    [Pg.131]    [Pg.261]    [Pg.529]    [Pg.242]    [Pg.581]    [Pg.49]    [Pg.22]    [Pg.6275]    [Pg.31]    [Pg.428]    [Pg.389]    [Pg.135]    [Pg.177]    [Pg.212]    [Pg.449]    [Pg.57]    [Pg.51]    [Pg.54]    [Pg.68]    [Pg.283]    [Pg.188]    [Pg.6274]    [Pg.238]    [Pg.246]    [Pg.12]    [Pg.133]    [Pg.1471]    [Pg.138]    [Pg.71]   
See also in sourсe #XX -- [ Pg.211 , Pg.213 ]




SEARCH



Similarity solution

© 2024 chempedia.info