Silver nitrate complexes

Silver fluoborate, reaction with ethyl bromide in ether, 46, 114 Silver nitrate, complexing with phenyl-acetylene, 46, 40 Silver oxide, 46, 83 Silver thiocyanate, 45, 71 Sodium amide, in alkylation of ethyl phenylacetate w ith (2-bromo-ethyl)benzene, 47, 72 in condensation of 2,4-pentanedione and 1 bromobutane to give 2,4-nonanedione, 47, 92 Sodium 2 ammobenzenesulfinate, from reduction of 2 mtrobenzenesul-finic acid, 47, 5... 

Silver nitrate complexed with ethylenediamine and glucose and other reducing agents have been used to grow silver films by SILAR. After annealing at 300 °C the films showed cubic structure and the I-V curves exhibited linear behavior, whereas the as-grown films showed nonlinear behavior.125... 

Silver fluoborate, reaction with ethyl bromide in ether, 46, 114 Silver nitrate, complexing with phenyl-acetylene, 46, 40 Silver oxide, 46, 83 Silver thiocyanate, 46, 71 Sodio-2-formyl-6-methylcyclohexanone, 48,41... 

The conversion of the m-monoolefin to its silver nitrate complex 1 was accomplished by adding 1.66 g. (0.010 mole) of the distilled reaction product to a solution of 1.70 g. (0.010 mole) of silver nitrate in 50 ml. of boiling methanol. The resulting solution, when cooled, deposited the complex as white needles, m.p. 79° dec. recrystallization from methanol separated 1.0 g. of the complex, m.p. 80° dec. After this complex had been partitioned between water and ether, the ether phase was separated, dried over magnesium sulfate, and concentrated. Distillation of the residual liquid in a short path still separated 0.45 g. of the pure (Note 6) cfs-cyclodecene, b.p. 70° (1.0 mm.), n B 1.4852. 

To a 1-1. separatory funnel is added ca. 500 ml. of 20% aqueous silver nitrate solution (100 g. of Mallinckrodt C.P. crystals to ca. 500 ml. of water). The pentane solution is added to the separatory funnel in five approximately equal portions, with intermittent shaking until all the silver nitrate complex has gone into solution (Note 15). 

Disilver Aeetylide + Silver Nitrate (Complex) (Silver Acetylide-Silver Nitrate), AgaCa AgNOj or AgjCjNOj, mw 409.67, N3.42%. Wh pdr,d 5.38(Ref 5) mp-deton ca 212 Ref 6). 

Disilver Acetylide 4 Six Silver Nitrates (Complex), AgjCj+6AgNOs or Cj Ag N60lft, crysts, mp-when heated to 308-327°it melts and then suddenly decomp with evoln of red fumes. Can be prepd by passing CaHa through a 30 soln of AgNOj in HaO or N/l HNOr It is not expl... 

The ligand properties of the related phosphonites P(OR)2R and phosphinites P(OR)R2 have attracted little attention.199,200 Reaction with silver chloride generally produced 1 1 complexes of the type AgCIL, whilst with silver nitrate, complex cations of the type AgL4 were generated. The products were characterized by elemental analysis, 7H and 31P NMR spectroscopy and conductivity measurements. 

Ligand exchange reactions have been used to prepare mercury(II) trialkylarsine complexes.202 Reaction of AgN03-AsMe3 with mercury halides gave the mercury arsine and silver halide (equations 10 and 11). The silver nitrate complex was not characterized. 

Mercuric Acetylide + Three Silver Nitrates (Complex), HgCj + 3AgNO. Wh crysts, decomp on heating without expln. Can be prepd by treating Ag2Cj + 6AgNOs with sufficient Hg(NOs)2 in HNOs soln to ppt the HgQ + 3AgNOs... 

A remarkable increase in the stability of pure phenylsilver is observed in comparison to that of the silver nitrate complex, with the compound surviving several days at room temperature under a nitrogen atmosphere. 

A. Allerhand and H. S. Gutowsky, Spin-echo NMR studies of chemical exchange. VL Rearrangement of bullvalene and of its silver nitrate complex. J. Am. Chem. Soc., 1965, 87(18), 4092-4096. 

The use of acetyl nitrate in place of sulfuric-nitric mixture as a nitrating agent leads to 1-nitro derivatives [28], These compounds have also been obtained by the nitration of 1-chlorobenzotriazole with a silver nitrate complex with trimethylphos-phite [273],... 

Note According to R.Vestin E.Ralf, Acta ChemScandinavica 3,106(1949) Beil 1, i910l this complex does not exist Monosilver Acetylide + Silver Nitrate (Complex), AgHCj. AgNO, or AgHCjNOj Solid, expl violently ca 230° Can be prepd from and an aq soln of silver nitrate, as described in Ref 2... 

Disilver Acetylide + Silver Nitrate (Complex) (Silver Acetylide-Silver Nitrate), AgjC,... 

The complexes formed by aliphatic and alicyclic di- and oligoolefins are often much more stable and more easily isolated as crystalline solids than those of the corresponding monoolefins. In many instances, the silver nitrate complex has been employed for isolation of the hydrocarbon from its synthesis mixture and sometimes for determination of the ring conformation (9, 225, 238, 408, 446). 

Both silver nitrate and molybdenum hexacarbonyl react with the nine-membered ring system m,m,m-cyclonona-l,4,7-triene to form complexes of the types (C9Hi2)-3 AgN03 and C9Hi2Mo(CO)3, respectively (2S8). In the assigned structures, based on NMR and related data, the silver nitrate complex has the silver ions associated with the outertt-orbital lobes (XLIII), while the molybdenum tricarbonyl complex has the molybdenum bonded to the inner 7r-orbital lobes (XLIV). In both complexes, a crown conformation of the ligand is assumed. 

Silver nitrate complexes are very useful for separation of the mixture of 1.3-, 1,4-, and 1,5-cyclooctadienes obtained by sodium-alcohol reduction of cycloocta-tetraene. The three adducts differ in stability in aqueous silver nitrate. All are stable at 0-5° that from the 1,3-diene dissociates at 30° that from the 1,4-diene dissociates above 60° that from the 1,5-isomer is stable at 90-100°. The pure dienes are recovered by steam distillation. 

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