Silver lead association

Gobalt occurs in the minerals cobaltite, smaltite, and erythrite, and is often associated with nickel, silver, lead, copper, and iron ores, from which it is most frequently obtained as a by-product. It is also present in meteorites. 

Georgius Agricola, a German scientist of the sixteenth century, was the first to mention bismuth detailing the melting of bismuth from ore (1). It was ia the sixteenth century that bismuth compounds were first discovered to have a soothing effect on stomach disorders. Bismuth compounds are stiU widely used ia preparations to reheve this condition. Not until the 1800s was bismuth refined and proven to be an element. Until that time, bismuth was usually referred to as one of the other elements with which it is associated ia ores such as antimony, silver, lead, and tin. 

Experience shows that in the deposition of a number of metals (mercury, silver, lead, cadmium, and others), the rate of the initial reaction is high, and the associated polarization is low (not over 20 mV). For other metals (particularly of the iron group), high values of polarization are found. The strong inhibition of cathodic metal deposition that is found in the presence of a number of organic substances (and which was described in Section 14.3) is also observed at mercury electrodes (i.e., it can be also associated with the initial step of the process). 

The total production of gold, silver and other associated base metals and silver/ gold production ratios from these deposits are summarized in Table 1.17. In addition to gold and silver, lead, zinc and manganese have been produced from some of the Se-type (e.g., Yatani) and copper has been produced from some of the Te-type (e.g., Teine, Kawazu). Total tonnage of production of Au and Ag from the Se-type is greater than... 

Silver Activation. Doping zinc sulfide with silver leads to the appearance of an intense emission band in the blue region of the spectrum at 440 nm, which has a short decay time. Weak luminescence in the green (520 nm) and red regions can also occur. The blue band is assigned to recombination at substitutionally incorporated silver ions [5.314], [5.315]. The red band is caused by luminescence processes in associates of silver ions occupying zinc positions with neighboring sulfur vacancies... 

Cobalt occurs in the minerals cobaltite, smaltite, and erythrite, and is often associated with nickel, silver, lead, copper, and iron ores, from which it is most frequently obtained as a by-product. It is also present in meteorites. Important ore deposits are found in Zaire, Morocco, and Canada. The U.S. Geological Survey has announced that the bottom of the north central Pacific Ocean may have cobalt-rich deposits at relatively shallow depths in water close to the Hawaiian Islands and other U.S. Pacific territories. 

Fluorspar occurs in two distinct types of formation in the fluorspar district of southern Illinois and Kentucky in vertical fissure veins and in horizontal bedded replacement deposits. A 61-m bed of sandstone and shale serves as a cap rock for ascending fluorine-containing solutions and gases. Mineralizing solutions come up the faults and form vein ore bodies where the larger faults are plugged by shale. Bedded deposits occur under the thick sandstone and shale roofs. Other elements of value associated with fluorspar ore bodies are zinc, lead, cadmium, silver, germanium, iron, and thorium. Ore has been mined as deep as 300 m in this district. 

The abundance of indium in the earth s cmst is probably about 0.1 ppm, similat to that of silver. It is found in trace amounts in many minerals, particulady in the sulfide ores of zinc and to a lesser extent in association with sulfides of copper, tin, and lead. Indium follows zinc through flotation concentration, and commercial recovery of the metal is achieved by treating residues, flue dusts, slags, and metallic intermediates in zinc smelting and associated lead (qv) and copper (qv) smelting (see Metallurgy, EXTRACTIVE Zinc and zinc alloys). 

Lead and 2inc minerals are so intimately mixed in many deposits that they are mined together and then separated. Silver minerals are frequendy found in association with galena. 

The most important body of primary silver ore in the United States in the 1990s is located in Silver Valley, the Coeur d Alene Mining District of Shoshone County, Idaho, which produces >200 t/yr of silver. The main ore mineral is tetrahedrite [12054-35-2] associated with sulfides of lead, copper, iron, and 2inc. 

Resources. World resources of silver are estimated to be about half a million tons. However, only about 250,000 metric tons are considered economically recoverable reserves. These are associated with ores of copper, gold, lead, and 2inc, and extraction depends on the economic recovery of those metals. Canada and the CIS vie for the greatest reserves of silver in the ground. 

Zinc minerals tend to be associated with those of other metals the most common ate zinc—lead or lead—zinc, depending upon the dominant metal, zinc— copper or copper—zinc, and base metal such as silver. Zinc does occur alone, most often in the northeastern district, and here, as elsewhere, recoverable amounts of cadmium (up to 0.5%) are present. Other minor metals recovered from zinc ores are indium, germanium, and thallium. 

Heubner, U. and Reinert, M., Effect of Small Silver Contents on the Characteristics of Lead and its Alloys , Pb80, Seventh International Lead Conference, Lead Development Association, London... 

Recently, Lacour, Sauvage and coworkers were able to show that the association of chiral [CuL2] complexes (L=2-R-phen,6-R-bpy and2-iminopyridine) with TRISPHAT 8 leads to an NMR enantiodifferentiation, which allows the determination of the kinetics of racemization of the complexes (bpy=2,2 -bipyri-dine phen=l,10-phenanthroline) [119]. This type of application has recently been reported in conjunction with chiral sandwich-shaped trinuclear silver(l) complexes [122]. Several reports, independent from Lacour s group,have confirmed the efficiency of these chiral shift agents [123-127]. Finally, TRISPHAT can be used to determine the enantiomeric purity of (r] -arene)chromium complexes. These results broaden the field of application of 8 to chiral neutral, and not just cationic, species [114,128,129]. 

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