SIFT

Figure A3.5.5. Rate constants for the reaction of Ar with O2 as a fiinction of temperature. CRESU stands for the French translation of reaction kinetics at supersonic conditions, SIFT is selected ion flow tube, FA is flowing afterglow and HTFA is high temperature flowing afterglow.

Unstable species such as O, FI and N atoms, molecular radicals and vibrationally excited diatomics can be injected by passmg the appropriate gas tluough a microwave discharge. In a SIFT, the chemistry is usually straightforward since there is only one reactant ion and one neutral present in the flow tube. 

These days, remarkably high-resolution spectra are obtained for positive and negative ions using coaxial-beam spectrometers and various microwave and IR absorption teclmiques as described earlier. Infonnation on molecular bond strengths, isomeric fonus and energetics may also be obtained from the teclmiques discussed earlier. The kinetics of cluster-ion fonuation, as studied in a selected-ion flow tube (SIFT) or by high-pressure... 

K has been identified as CFl200I-I from its chemistry the reaction mechanism is insertion [115], Collision-induced dissociation (in a SIFT apparatus, a triple-quadnipole apparatus, a guided-ion beam apparatus, an ICR or a beam-gas collision apparatus) may be used to detemiine ligand-bond energies, isomeric fomis of ions and gas-phase acidities. 

Adams N G and Smith D 1976 The selected ion flow tube (SIFT) a technique for studying ion-neutral reactions Int J. Mass Spectrom. Ion Phys. 21 349... 

Smith D and Adams N G 1988 The selected ion flow tube (SIFT) studies of ion-neutral reactions Adv. At Mol. Phys. 24 1-49... 

Adams N G and Smith D 1988 Flowing afterglow and SIFT Techniques for the Study of Ion-Molecule Reactions ed J M Farrar and W FI Saunders Jr (New York Wiley)... 

A sehematie diagram of a SIFT apparatus is shown in figure Bl.7.12. The instrument eonsists of five basie regions, the ion soiiree, initial quadnipole mass filter, flow tube, seeond mass filter and finally the deteetor. The heart of the instrument is the flow tube, whieh is a steel tube approximately 1 m long and 10 em in diameter. The pressure in the flow tube is kept of the order of 0.5 Torr, resulting in earrier gas flow rates of... 

Figure Bl.7.12. A schematic diagram of a typical selected-ion flow (SIFT) apparatus. (Smith D and Adams N G 1988 The selected ion flow tube (SIFT) studies of ion-neutral reactions Advances in Atomic and Molecular Physics vol 24, ed D Bates and B Bederson p 4. Copyright Academic Press, Inc. Reproduced with pennission.)...

Spanel P and Smith D 1997 SIFT studies of the reactions of FijO", NO and Ot with a series of alcohols Int. J. Mass Spectrom. Ion Proc. 167/168 375-88... 

H2 sift-proof woven plastic bag 6PB1 within a steel crate or box within an aluminum dmm... 

L2 sift-proof textile bag 6PD2 within a wickerwork hamper... 

M1 multiwaU bag of at least three pHes, sift-proof 6PG2 6PH1 within a fiberboard box... 

The primary mechanisms responsible for most particle segregation problems are sifting, particle velocity, air entrainment, particle entrainment, and dynamic effects (14). 

Sifting may occur while a pile is being formed. Fine particles are concentrated in the center under the fill point. However, as the pile is formed, the slope stabihty is such that layers of finite thickness intermittently move from the central fill point, carrying some of the finer particles with them. 

On a chute, higher drag results in lower particle velocity which can be accentuated by stratification on the chute surface because of the sifting mechanism. Concentrations of smaller particles close to the chute surface and larger particles at the top of the bed of material, combined with the typically higher frictional drag of finer particles, often result in a concentration of fine particles close to the end of the chute, and coarse particles farther away. This can be particulady detrimental if portions of the pile go to different processing points, as is often the case with multiple outiet bins or bins with vertical partitions. 

Another technique is to change the particle size distribution. There are, however, disadvantages. If segregation is occurring by the sifting mechanism, the particles must be almost identical in size before sifting is prevented. Alternatively, the mean particle size can be reduced below 100 p.m, but this size reduction (qv) increases the probabiUty of segregation by the too fine powder mechanisms. 

Roll mills are employed in a wide variety of applications for medium-coarse down to fine size reduction. By far the most prevalent use is in flour milling where banks of roU mills, beginning with coarse profiles and ending with smooth roUs, are used in series with sifting machines to extract the white flour from the associated bran. 

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