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Side Chain Functionalization Using Metal Coordination

The previous section described the supramolecular side chain functionalization of polymers based on a single recognition motif. However, biological systems use a wide variety of noncovalent interactions such as hydrogen bonding, metal coordination, and hydrophobic interactions in an orthogonal fashion to introduce function,... [Pg.111]

Figure 5.5 Side chain functionalization of diblock copolymers 1 and 2, using a combination of hydrogen bonding and metal coordination.

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Coordinate functions

Coordinating functional

FUNCTIONALIZED CHAINS

Functional side chains

Metal chains

Metal functions

Metalation chains

Metallic chain

Metals used

Side-chain functionalized

Side-chain metallation