Shrinkage marks

Abrupt changes of section cause poor flow and differential shrinkage, giving sink marks (Fig. 28.11 - you can find them on the surface of many small polymer parts), distortion, and internal stress which can lead to cracks or voids. The way out is to design in the way illustrated in Fig. 28.12. Ribs, which are often needed to stiffen polymer parts, should have a thickness of no more than two-thirds of the wall thickness, and a height no more than three times the wall thickness. Corners are profiled to give a uniform section round the corner. 

As reviewed there is much to consider. Examples include cooling as the product sets up results in different shrinkage rates for thicker versus thinner sections in the different processes. This results in either external waviness or sink marks, or warpage and internal voids, as the product contracts. Flat surfaces are difficult to maintain but not impossible to attain using certain processes. High speed of flow to fill the cavity of the mold is impeded going around square corners, so provision for radii and fillets are important. 

These cements have marked creep characteristics and flow under pressure even when fully set. In this they contrast markedly with the rigid phosphate cements (Wilson Lewis, 1980). This plastic behaviour explains why such cements provide a good seal despite a high setting shrinkage and thermal expansion of 35 x 10 °C" (Civjan Brauer, 1964). 

As one might expect the rate of p-nitrophenyl heptanoate hydrolysis increased at low ethanol concentrations as a result of apolar binding. The rate of p-nitrophenyl acetate hydrolysis also increased markedly at low ethanol concentration. This finding was explained by a conformational effect on the polymer, that is, lower ethanol concentration brings about a shrinkage of the polymer, which increases concerted interactions of the imidazole residues. The hydrolysis of 3-nitro-4-dodecanoyloxybenzoate was found to be 1700 times faster in the presence of poly[4(5)-vinylimidazole] compared to free imidazole (77). A double-displacement mechanism was demonstrated for this system (75). 

Figure 5 gives the variation of the atomic volume in the actinide series, for the room temperature crystal structures as well as for the ccp and bcc high temperature allotropes, which exist for a number of actinides. The graph is based on the lattice parameters of Table 1, which includes also recent results. The marked dip in the curve from Th to Am illustrates the shrinkage of interactinide distance which is linked to the itinerancy of the 5f electrons in this part of the actinide series. 

Simha and Zakin (126), Onogi et al (127), and Comet (128) develop overlap criteria of the same form but with different numerical coefficients. Accordingly, flow properties which depend on concentration and molecular weight principally through their effects on coil overlap should correlate through the Simha parameter c[ /], or cM , in which a is the Mark-Houwink viscosity exponent (0.5 < a < 0.8). If coil shrinkage, caused by the loss of excluded volume in good... 

Avoid thick sections. Thick sections add to the material cost and increase sink marks caused by shrinkage. 

Fig. 15.20. Registration marks on PEN after a full OTFT process. Shrinkage can be determined by measuring the offsets.

Not only may the rate of cooling be slow it also may vary from one part of the moulding to another, and this can have marked effects on the crystalline morphology, molecular orientation, shrinkage—and consequently on the qualities and appearance of products. If, for example, the rate of crystallization differs in different parts of a moulding the sizes of crystals also will differ, and its clarity will be impaired. 

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