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Shrinkage isotropic

Other MFl-type zeolite-sorbate systems are known to exhibit similar behavior. In a recent study, Yu et al. [34] reported that at saturated loadings of -hexane a single MFl-type zeolite unit cell has an overall volume expansion of 2.3%, which can correlate to shrinkage in non-zeoUtic pores up to 7 nm for a 1 tm crystal when isotropic expansion is assumed. It was demonstrated that, even in membranes with large number of defects, the crystallite swelling caused the membrane to achieve significant separation between n-hexane and trimethylbenzene, iso-octane and 2,2-dimethylbutane using pervaporation [34]. [Pg.320]

The nature and type of initiation scheme plays an important role in the performance of the adhesive [194,202-204]. Stresses due to polymerization shrinkage lead to the creation of a gap between the adhesive and tooth material. In the case of bulk chemical initiation, shrinkage stresses tend to create gaps at all interfaces, drawing material inward isotropically. With a photoinitiation scheme, polymerization begins at the free surface and pulls the material away from the dentin towards the free surface [194]. Thus the gap is created at the... [Pg.20]

When shrinkage is isotropic, the linear shrinkage (AL/Lq) is calculated from the volume shrinkage as ... [Pg.706]

Figure 10.29 shows displacement offset vectors after subtracting the effects of rigid translations and rotations and isotropic shrinkage of the stamp (Root mean... [Pg.263]

Table II also indicates that the actual part shrinkages fall between the limits predicted by the linear CTE s for the melt temperature and mold temperature cooling to room temperature cases. In the flow direction, shrinkage appears to be best modeled as part cooling from the mold temperature. For the transverse and thickness directions, cooling from the melt temperature may more closely approximate the shrinkage. This is an important result because a part of more complex geometry may be more isotropic in nature and could, as a consequence of conservation of volumetric CTE, have considerably larger shrinkage than that predicted from flow and transverse direction shrinkages alone. Table II also indicates that the actual part shrinkages fall between the limits predicted by the linear CTE s for the melt temperature and mold temperature cooling to room temperature cases. In the flow direction, shrinkage appears to be best modeled as part cooling from the mold temperature. For the transverse and thickness directions, cooling from the melt temperature may more closely approximate the shrinkage. This is an important result because a part of more complex geometry may be more isotropic in nature and could, as a consequence of conservation of volumetric CTE, have considerably larger shrinkage than that predicted from flow and transverse direction shrinkages alone.
The cell wall of wood can be considered to consist of a non-crystalline matrix of lignin and hemicelluloses in which strong, stiff cellulosic microfibrils are embedded. The crystalline microfibrils exhibit no tendency either to adsorb moisture or to change in length or cross-section. On the other hand the non-crystalline isotropic matrix can lose and gain water and shows a considerable tendency to shrink and swell. In isolation one would expect the matrix to shrink or swell equally in all directions, that is Ox = Oy = = tto and Ovoi = 3ao i.e. ao is the isotropic shrinkage in... [Pg.103]


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