Shock sensitive explosives

A very shock sensitive explosive, containing nearly 90 wt% of nitrogen. See other high-nitrogen compounds, non-metal azides... 

The dry peroxide polymer (formed in ozonisation of vinyl acetate, and possibly a dioxirane polymer) is a shock-sensitive explosive, which needs care in handling. 

It is a moderately shock-sensitive explosive which has exploded during distillation [1], A series of its esters, expected to be explosive, was prepared [2], and explosive ether and ester derivatives are reviewed [3]. 

It is a pyrophoric and treacherously shock-sensitive explosive, especially as the dry black form. It will deflagrate under nitrogen or argon when scratched with a spatula, and ignites in contact with poly(chlorotrifluoroethylene), (Fluorolube). The caesium and rubidium salts are not shock-sensitive but will deflagrate on friction and are... 

Nielsen, A. T. et al., J. Org. Chem., 1979, 44, 2503-2504 A very shock-sensitive explosive which melts at 152°C, then decomposes explosively. 

The salt is a heat and shock-sensitive explosive. Attempts to prepare it from trimethylplatinum hydroxide and perchloric acid led to violent explosions at higher acid concentrations. 

In the liquid phase, it is an extremely friction- and shock-sensitive explosive [1], like the trichloro analogue [2],... 

A shock-sensitive explosive complex is formed, which could not be characterised. Iodine... 

Christe, K. O. et al., Inorg. Chem., 1987, 26, 920 A shock-sensitive explosive, which needs full handling precautions. 

Mixtures of inorganic oxygenated compounds (halide oxides or oxide sulfides) or oxygen-rich organic compounds (alkyl oxalates) with sodium (or its alloy with potassium) are shock-sensitive explosives. 

Many aromatic 3-cyanotriazenes are shock-sensitive, explosive compounds. 

All the N—F compounds involved in the synthesis of a group of C3—C7N-trilluoroalky lam idincs were shock-sensitive explosives in varying degrees. Several were only stable in solution, and others exploded dining analytical combustion. Individually indexed compounds are ... 

The lower third of the chart (up to Tq-Tj = 1,000°K) contains hazardous explosives or materials with an NFPA rating of 3 or 4 (shock sensitive explosive materials). The single exception is hydrogen cyanide with an NFPA rating of 2 (unstable, capable of violent chemical change, but does not detonate)... 

More powerful and less shock sensitive explosives are continually being sought for both military and commercial use and work on octanitrocubane (ONC) [Structure (2.62)] is a meaningful step in this direction. ONC is a nitro derivative of... 

The latter two reactions demonstrate the possibility of using thianthrenium perchlorate in preparing magnet-active ion radicals with two or even three unpaired electrons and positive charges. (At this point one very important caution has to be stated Thianthrenium perchlorate is a shock-sensitive explosive solid and should be handled with care.)... 

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