44 selection 366 visible light

Figure 2. UV light-induced deposition of silver nanoparticles (al-a3) and wavelength-selective visible light-induced dissolution of silver nanoparticles (bl-b3).

The cholesteric phase maybe considered a modification of the nematic phase since its molecular stmcture is similar. The cholesteric phase is characterized by a continuous change in the direction of the long axes of the molecules in adjacent layers within the sample. This leads to a twist about an axis perpendicular to the long axes of the molecules. If the pitch of the heHcal stmcture is the same as a wavelength of visible light, selective reflection of monochromatic light can be observed in the form of iridescent colors. 

Visible and ultraviolet absorption spectra are measured in an absorption spectrometer. The source gives out intense visible light or ultraviolet radiation. The wavelengths can be selected with a glass prism for visible light and with a quartz prism or a diffraction grating for ultraviolet radiation (which is absorbed by glass). A typical absorption spectrum, that of... 

In this chapter, photoelectrochemical control of size and color of silver nanoparticles, i.e., multicolor photo-chromism [1], is described. Silver nanoparticles are deposited on UV-irradiated Ti02 by photocatal5dic means [2]. Size of the nanoparticles can be roughly controlled in the photocatalytic deposition process. However, it is rather important that this method provides nanoparticles with broadly distributed sizes. The deposited silver nanoparticles are able to be dissolved partially and reduced in size by plasmon-induced photoelectrochemical oxidation in the presence of an appropriate electron acceptor such as oxygen. If a monochromatic visible light is used, only the particles that are resonant with the light are dissolved. That is, size-selective dissolution is possible [3]. This is the principle of the multicolor photochromism. 

These detectors are based on selective absorption of ultraviolet or visible light by the desired solute. A large number of single or multiple wavelength... 

Most dyes and pigments owe their colour to the selective absorption of incident light. In some compounds, colour can also be observed as a result of the emission of visible light of specific wavelengths. These compounds are referred to as luminescent. The most commonly encountered luminescent effects are fluorescence and phosphorescence. The transitions which can occur in a molecule exhibiting either fluorescence... 

Apart from a few applications, such as UV disinfection and lacquer hardening, the intensity of UV radiation is well below that of visible light in ambient daylight or indoor lighting. A UV sensor must therefore be insensitive to visible light, otherwise the detection signal would easily be drowned out by the visible fraction of the radiation spectrum. Sensors that fulfill this requirement have a selective spectral sensitivity in the UV range. There are two important selectivities, known as visible-blindness and solar-blindness. 

Blatter, F., Sun, H. and Frei, H. (1996). Highly selective formation of tert-butyl hydroperoxide from the reaction of isobutane and 02 in a zeolite under visible light. Chem. Eur. J. 2, 385-389... 

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