Secondary building units metal-organic frameworks

Eddaoudi M., Moler D. B., Li Hailian, Chen Banglin, Reineke T. M., O Keeffe M. and Yaghi O. M., Modular Chemistry Secondary building units as a basis for the design of highly porous and robust metal-organic carboxylate frameworks, Acc. Chem. Res. 34 (2001) pp. 319-330. 

Rosi, N.L., Kim, J., Eddaoudi, M., Chen, B., O Keeffe, M., and Yaghi, O.M. (2005) Rod packings and metal-organic frameworks constructed from rod-shaped secondary building units. Journal of the American Chemical Society, 111 (5), 1504-1518. 

L.N. Rosi, M. Eddaoudi, J. Kim, M. O Keeffe, and O.M. Yaghi, Infinite Secondary Building Units and Forbidden Catenation in Metal-organic Frameworks. Angew. Chem., Int. Ed., 2002, 41, 284-287. 

Tranchemontagne DJ, Mendoza-Cortes JL, O Keeffe M et al (2009) Secondary building units, nets and bonding in the chemistry of metal-organic frameworks. Chem Soc Rev 38 1257-1283... 

Su Z, Chen S-S, Fan J et al (2010) Highly cormected three-dimensional metal-organic frameworks based on polynuclear secondary building units. Cryst Growth Des 10 3675-3684... 

Xu J, Su W, Hong M (2011) A series of lanthanide secondary building units based metal-organic frameworks constructed by organic pyridine-2,6-dicarboxylate and inorganic sulfate. Cryst Growth Des 11 337-346... 

Yang E-C, Li J, Ding B et al (2008) An eight-coimected 3d lead(ii) metal-organic framework with octanuclear lead(ii) as a secondary building unit synthesis, eharacterization and luminescent property. CrystEngComm 10 158-161... 

AAS = atomic absorption spectroscopy ATOF-MS = aerosol time-of-flight mass spectrometry 2,6-ndc = 2,6-naphthalenedicarboxylate bdc = 1,4-benzenedicar-boxylate bpdc = 1,3,5-benzenetricarboxylate bpydc = 2,2 -bipyridine-5,5 -dicarboxylate btb = 4,4, 4"-benzene-1,3,5-triylbenzoate btc = 1,3,5-benzenetricarboxylate 3D = three-dimensional dabco = l,4-diaza[2.2.2]bicyclo-octane EDX = energy-dispersive X-ray spectroscopy EXAFS = extended X-ray fine structure Fc = ferrocenyl ICP-AES = inductively coupled plasma atomic emission spectroscopy MOF = metal-organic framework PSD = postsynthetic deprotection PSM = Postsynthetic modification PXRD = Powder X-ray diffraction 1,4-ndc = 1,4-naphthalenedicarboxylate SALE = solvent-assisted linker exchange SBU = secondary building unit ... 

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