Schadt

Schadt M and Flelfrich W 1971 Voltage-dependent optical activity of a twisted nematic liquid crystal Appl. Phys. Lett. 18 127-8... 

Our next concern is the solvent nucleophilicity. Schadt et al. " chose the solvolysis of methyl tosylate, which should be an Sn2 process, as the defining process. For this standard reaction the parameter / in Eq. (8-69) was set at 1.00. An empirical estimate of m, describing the sensitivity of methyl tosylate to solvent ionizing power, was obtained as the slope of the two-point line for methyl tosylate solvolysis in... 

The last three columns contain the parameters which give the most reliable information on the nucleophilic character of the solvent for a wide range of solvents, namely Koppel and Paju s -values (1974), Schleyer s iVBS-values (Schadt et al., 1976), and Taft s / -values (Kamlet et al., 1983). The columns showing the type of product demonstrate roughly that increasing nucleophilicity favors the formation of products of homolytic intermediates. The fact that there is no exact correlation with nucleophilicity is likely to be due to the (one-) electron transfer capabilities of these solvents, which do not parallel the nucleophilicity (see Sec. 8.6). 

Schadt EE, Lamb J, Yang X, Zhu J, Edwards S, Guhathakurta D, et al. An integrative genomics approach to infer causal associations between gene expression and disease. Nat Genet 2005 37 710-7. 

Oxidation rate constant k, for gas-phase second order rate constants, k for reaction with OH radical, kNQ3 with N03 radical and k()3 with 03 or as indicated, data at other temperatures see reference k03 = 0.90 x 10-17 cm3 molecule-1 s-1 at room temp. (Cadle Schadt 1952)... 

DF Williams and M Schadt, DC and pulsed electroluminescence in anthracene and doped... 

M Schadt, Liquid crystal materials and liquid crystal displays, Anna. Rev. Mater. Set, 27 305-379, 1997. 

Chuan-Jian Zhong, Jin Luo, Mathew M. Maye, Nancy Kariuki, Lingyan Wang, Derrick Mott, Peter Njoki, Mark Schadt, Stephanie I-Im. Lim, and Yan Lin... 

J. Luo, M. M. Maye, N. N. Kariuki, L. Wang, P. Njoki, Y. Lin, M. Schadt, H. R. Naslund, and C. J. Zhong, Electrocatalytic oxidation of methanol Carbon-supported gold-platinum nanoparticle catalysts prepared by two-phase protocol, Catal. Today 99, 291-297 (2005). 

Mark Schadt, Department of Chemistry, State University of New York at Binghamton, Binghamton, NY 13902... 

R. Schadt, Process analytical technology - changing the validation paradigm. Pharmaceutical Rev. 7(1) 58-61, January/February (2004). 

Schadt EE, Monks SA, Drake TA et al. Genetics of gene expression surveyed in maize, mouse and man. Nature 2003 422 297-302. 

Schadt EE, Monks SA, Friend SH. A new paradigm for drug discovery integrating clinical, genetic, genomic and molecular phenotype data to identify drug targets. Biochem Soc Trans 2003 31 437 43. 

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