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Scattering cross section Single atom

Applications that would benefit from the described achievements are commonly bottlenecked by a lack of general procedures to interpret intensity data. Recently, it was suggested to interpret STEM data by extraction of single atom scattering cross sections For HRTEM, Figure 8 highlights a suitable method for intensity quantification from reconstructed electron exit waves. [Pg.28]

Fig. 27. Measured total diffuse differential scattering cross-section of single crystal sapphire and ruby (1.26% atomic Cr). A = 6.0A. The statistical error is indicated. Total counting time was 48 hours [after Ref. (/ 7)]... Fig. 27. Measured total diffuse differential scattering cross-section of single crystal sapphire and ruby (1.26% atomic Cr). A = 6.0A. The statistical error is indicated. Total counting time was 48 hours [after Ref. (/ 7)]...
To examine the role of the LDOS modification near a metal nanobody and to look for a rationale for single molecule detection by means of SERS, Raman scattering cross-sections have been calculated for a hypothetical molecule with polarizability 10 placed in a close vicinity near a silver prolate spheroid with the length of 80 nm and diameter of 50 nm and near a silver spherical particle with the same volume. Polarization of incident light has been chosen so as the electric field vector is parallel to the axis connecting a molecule and the center of the silver particle. Maximal enhancement has been found to occur for molecule dipole moment oriented along electric field vector of Incident light. The position of maximal values of Raman cross-section is approximately by the position of maximal absolute value of nanoparticle s polarizability. For selected silver nanoparticles it corresponds to 83.5 nm and 347.8 nm for spheroid, and 354.9 nm for sphere. To account for local incident field enhancement factor the approach described by M. Stockman in [4] has been applied. To account for the local density of states enhancement factor, the approach used for calculation of a radiative decay rate of an excited atom near a metal body [9] was used. We... [Pg.165]

The INS intensity, 5 (g,fo), as calculated from the Scattering Law, Eq. (2.41), is related to the mean square atomic displacements, weighted by the incoherent scattering cross sections. What is required to calculate this quantity is the mean square atomic displacement tensor, Bi, and this can be obtained from the crystalline equivalent of L/ " ( A2.3), the normalised atomic displacements in a single molecule Eq. (4.20). This is and was introduced above, in Eq. (4.55). We have seen how... [Pg.165]

Fig. 10. Theoretical absorption coefficient for a cluster formed by the central Mn and six oxygens. Going from top to bottom the total cross section, the atomic contribution (dotted-dashed line), the single scattering contribution, n = 2, (EXAFS) and the contributions of successive orders of multiple scattering pathways of orders n = 3,4 and 5 are shown... Fig. 10. Theoretical absorption coefficient for a cluster formed by the central Mn and six oxygens. Going from top to bottom the total cross section, the atomic contribution (dotted-dashed line), the single scattering contribution, n = 2, (EXAFS) and the contributions of successive orders of multiple scattering pathways of orders n = 3,4 and 5 are shown...
With the Fourier difference method, data obtained from single-crystal neutron diffraction provide a full view of the probability density of the H(D) atoms. For this purpose, once the crystal structure has been determined, Bragg peak intensities can be calculated for an ideal crystal in which the scattering cross-section of the H(D) atoms of the methyl groups is set to zero. The difference from the original pattern contains specific information on the methyl H(D) atoms. Further Fourier back-transformation gives the probability density distribution in direct space (see Figure 8.16). [Pg.293]


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