Satellite dots

Group (c) satellites (dotted). These arise from electron correlation effects which are beyond the FISCI mechanism. The large spatial overlap between orbitals with the same principal quantum number n =v3 still favours electron correlation effects between 3s3p6 and 3s23p43d, but ISCI and FSCI are responsible for the presence of 3s23p43d 2S+1Le final ionic states with symmetries different from 2Se. Most of these states can be identified in the electron spectrum. 

Several defects associated with the automated dispensing of adhesives are possible, among which are stringing, tailing, missing dots, satellite dots. 

Figure 2 Valence ADC[3] ionization spectra (full lines) of the (a) ethylene, (b) butadiene, (c) hexatriene and (d) octatetiaene compounds in their all-trans configuration (6-31G results). The dotted curves represent the partial contribution to the convoluted density of states arising from satellites with Tq < 0.40. ...

Fig. 56. TEM images of DNA-linked gold network (a) an assembly of 8 and 30 nm gold particles (b) higher resolution image of (a) (c) control experiment without DNA (d) HR-TEM image of a portion of a hybrid Au/quantum dot (QD) assembly. The lattice fringes of the QDs, which resemble fingerprints, appear near each Au nanoparticle, (e) A satellite structure formed using a 60-fold excess of the 8 nm particles. Reproduced with permission from Ref. (185). Copyright 2000, American Chemical Society.

Fig. 1. The core particle, the DNA superhelix and H2B and H3 N-terminal tails, (a) Space-filling representation of the 2.8 A crystal structure of the 146 bp human a-satellite nucleosome core particle [22]. The dyad is in the plane of the paper and the superhelix axis slightly off that plane. Positive and negative numbers mark the superhelix locations (SHL) in the upper and lower gyres, respectively, and the dotted curve follows the path of the double helix axis, (b) Ribbon representation of the DNA superhelix slit along a line parallel to its axis, opened out and laid flat on the paper surface. SHL are also indicated, together with H2B and H3 tails passage points between the gyres. (From Fig. 5 in Ref [29].)...

Clearly, 254 K is much colder than the typical temperatures around 288 K (15°C) found at the earth s surface. This difference between the calculated effective temperature and the true surface temperature is dramatically illustrated in Fig. 14.4, which shows the spectra of infrared radiation from earth measured from the Nimbus 4 satellite in three different locations, North Africa, Greenland, and Antarctica (Hanel et al., 1972). Also shown by the dotted lines are the calculated emissions from blackbodies at various temperatures. Over North Africa (Fig. 14.3a), in the window between 850 and 950 cm-1, where C02, O-, HzO, and other gases are not absorbing significantly, the temperature corresponds to blackbody emission at 320 K due to the infrared emissions from hot soil and vegetation. 

FIGURE 14-4 Infrared emission from earth measured from the Nimbus 4 satellite (a) over the Niger Valley, North Africa (14.8°N, 4.7°W) at 12 00 GMT (b) over Greenland (72.9 LN, 41.1°W) at 12 18 GMT, and (c) over Antarctica (74.6°S, 44.4°E) at 11 32 GMT. Emissions from blackbodies at various temperatures are shown by the dotted lines for comparison (adapted from Hanel et at., 1972). 

Figure 1 X-ray and 7-ray fluxes for Model 10H (no mixing). The numbers (with the solid curves) indicate the energy bands in keV the dotted curve is for the 7-ray line at 847 keV and the dashed curve is for the Fe Ka line at 6.4 keV. The 5

Fig. 7.7. The difference between the satellite wavelengths and the resonance line wavelengths in Ar16+ as a function of n, for the three satellite groups, along with the theoretical wavelengths. The measured values for An, Bn and C are depicted as asterisks, triangles and dots, respectively. The satellite group A3 is shown as the x. The theoretical wavelength differences are shown by the curves, with the calculated value for A3 (from RELAC) given by the dot. The solid lines are from MZ, while the dotted lines are from RELAC...

Fig. 7.10. Linear and log spectra in the vicinity of 4D in Mo32+ are shown in the top frame. Also shown is the synthetic collisional-radiative synthetic spectrum, with Ne-like lines shown in solid, Na-like transitions depicted by the dotted lines, the Mg-like transition shown as the dashed line and F-like transitions shown by dash-dot lines. The spectrum of the Kr26+ 4C, 4D and 4F transitions, with Na-and Mg-like 2p -4d satellites is shown in the bottom frame. Also shown is the synthetic spectrum, with Ne-like lines shown in solid, Na-like transitions depicted by the dotted lines and the Mg-like 2p -4d transition shown as the dashed line...

In a recent article the satellite profile and its temperature dependence are calculated for various analytical representations of the potential difference between upper and lower states and of the oscillator strength (15). By varying the parameters of these analytical forms we have tried to fit the experimental profile and its temperature dependence. For example, the left hand curve of Figure 4 gives the best fit of the experimental profile (dotted line) obtained for the Cs-Ar pair. The potential of the upper state used for this fit (dotted line) is plotted in Figure 4b and is seen to extrapolate to the one deduced from the quasistatic interpretation (full line). Such agreement is unobtainable (j[5) if other quite different parameters are used, and consequently this method can provide useful information from the satellite region. 

Fig. 25. Emission spectra (time-integrated) of (a) Pt(2-thpy-hg)2 and (b) Pt(2-thpy-dg)2 dissolved in n-octane (Shpol skii matrix) at a concentration of 10 mol/1. Ag c = 457.9 nm. The wavenumber scale gives the separation from the respective electronic origin I (set to zero). For both compounds, origin I does not carry any emission intensity. All vibrational satellites that correspond to fundamentals are false origins, i. e. they are vibronically (Herzberg-Teller) induced. Several vibrational modes of the perprotonated compound are correlated to those of the perdeuterated one, they are connected by dotted lines. The spectrum (a) corresponds to the one reproduced in Fig. 13. (Compare Ref. [23])...

Figure 17 Spectral expansions of " Sn NMR spectra recorded at 93.2 MHz of 1 in CDCI3 solution at room temperature. Bold dots represent "y(" Sn," /" Sn) coupling satellites, open circles represent V( Sn," Sn) coupling satellites, open triangles represent /(" Sn, Q satellites and asterisks represent resonances from further unidentified minor species. The main resonances of M, mj and m2 are vertically out of scale. M, m, m2 and m3 represent the four spedes observed at room temperature, as identified from the spectral data. (Reproduced with permission from ref. 17)...

FIGURE 4-18 Tracing of a satellite photo showing cloud formation along fronts, as well as the relationship between low-pressure areas (cyclones) and fronts. Note the correspondence between the cyclones and fronts in this figure and the idealized patterns shown later in Fig. 4-20 for the genesis of a cyclone. Pressures are in millibars dotted lines show the west coast of North America and Hudson Bay (adapted from FAA, 1965). 

Figure 5. Photoelectron spectra of the Ln3dA/2 and An4d.5/2 levels of H[LnPc2]-(Ln = La, Ce, Pr, and Nd) and AnPc2 (An = Th and U). Deconvolution of the satellite structure is given by the dotted line.

Lorentzian line shapes with a typical half-width of 300 kHz were assumed for the satellites and each multiplet was weighted with its appropriate Boltzmann probability. For comparison the corresponding AM = 0 multiplet, in the absence of the translational Zeeman effect, is shown by the dotted curve... 

FIGURE 5.6 (a) Vertical profiles of N20 over the tropics at equinox circa 1980. Circles denote balloonbome measurements at 9°N and 5°S squares represent aircraft measurements between 1.6°S and 9.9°N. Dashed curve refers to the average of satellite measurements at 5°N, equinox, between 1979 and 1981. This compilation of data was presented by Minschwaner et al. (1993), where the original sources of data can be found. The dotted curve indicates the vertical profile used by Minschwaner et al. to estimate the lifetime of N20. (b) Calculated diumally averaged loss rate for N20 (in units of 1012 molecules cm 3 s ) as a function of altitude and latitude, at equinox. The loss rate includes both photolysis and reaction with O( D) (Minschwaner et al. 1993). 

A lattice vibration of wave number k reduces the structure factor at the lattice wave numbers (solid dots), but introduces a new structure factor at satellite points differing from the lattice wave numbers by k. 

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