Salicylaldehyde methyl ether

SYNS 2-ANISALDEHYDE BENZALDEHYDE, 2-METHOXY-(9CI) o-METHOXYBENZALDEHYDE 2-METHOXYBENZALDEHYDE 6-METHOXY-BENZALDEHYDE 2-METHOXYBENZENE-CARBOXALDEHYDE SALICYLALDEHYDE METHYL ETHER... [Pg.85]

SALICYLALDEHYDE METHYL ETHER see AOT525 SALICYLIC ACID see SAIOOO m-SALICYUC ACID see HJIlOO SALICYLIC ACID, 3,5-DINITRO- see HKE600 SALICYLIC ACID, ISOBUTYL ESTER see IJNOOO SALICYLIC ACID, ISOPENTYL ESTER see IMEOOO SALICYLIC ACID, METHYL ESTER see MPIOOO SALICYLIC ACID with PHYSOSTIGMINE (1 1) see PIA750... [Pg.1872]

Methoxybenzenecarboxaldehyde Methyl salicylaldehyde Salicylaldehyde methyl ether Empihcal C8Hs02 Formula C6H4(OCH3)CHO Properties Colorless or cream-colored cryst., faint sweet floral odor, spice-like flavor sol. in alcohol insol. in water m.w. 136.15 dens. 1.1326 m.p. 35-37 C b.p. 243-244 C flash pt. 117 C ref. index 1.560... [Pg.2555]

Salicylaldehyde methyl ether. See o-M eth oxy benza I dehyde Salicylamide... [Pg.3870]

Other Names Benzaldehyde, o-methoxy- o-Anisaldehyde 2-Anisaldehyde 2-Melhoxybenzalde-hyde 2-Methoxybenzenecarboxaldehyde 2-Methoxyphenylformaldehyde 6-Melhoxybenzaldehyde NC 064 NSC 58960 Salicylaldehyde methyl ether o-Formylanisole o-Methoxybenzaldehyde CA Index Name Benzaldehyde, 2-methoxy-CAS Registry Number 135-02-4 Merck Index Number Not listed Chemical Structure... [Pg.221]

Contrasting stereoselectivity is observed for the reaction of salicylaldehyde and its methyl ether (Scheme 11). " The anti selective aUylation for salicylaldehyde methyl ether may be attributed to a transition state I and the syn selective aUylation of salicylaldehyde may be attributed to a transition state II (Scheme 11). " ... [Pg.285]

Reaction of the potassium salt of salicylaldehyde with chlo-roacetone affords first the corresponding phenolic ether aldol cyclization of the aldehyde with the ketonic side chain affords the benzofuran (1). Reduction of the carbonyl group by means of the Wolf-Kischner reaction affords 2-ethyl-benzofuran. Friedel-Crafts acylation with anisoyl chloride proceeds on the remaining unsubstituted position on the furan ring (2). The methyl ether is then cleaved by means of pyridine hydrochloride (3). lodina-tion of the phenol is accomplished by means of an alkaline solution of iodine and potassium iodide. There is thus obtained benziodarone (4)... [Pg.314]

Experiments.—To an ice-cooled solution of 2-3 g. of a phenol (phenol, cresol, /3-naphthol, salicylaldehyde, quinol) in a little ether, acetone, or methyl alcohol, the diazomethane solution prepared as described above is added in small portions until evolution of gas no longer takes place and the solution is coloured faintly yellow. [Pg.273]

Salicylaldehyde reacts with trimethylsilylketene dithioacetal in the presence of a Lewis acid to form the chroman 502, the product of a deoxygenative divinylation (Equation 208) <2001JOC3924>. This reaction can also be applied to salicylaldimines <2003JOC4947>. Treatment of 3,5-dibromosalicylaldehyde with methyl vinyl ketone (MVK) in the presence of DABCO leads to a chroman-4-ol as the major product <2002J(P1)1318>. A stereoselective one-pot synthesis of vy/z-fused chromans from salicylaldehydes, aromatic amines and cyclic enol ethers is carried out in the... [Pg.522]

Maltol Isobutyrate 2-Methoxy 3-(or 5- or 6-) Isopropyl Pyrazine 5H-5-Methyl-6,7 -dihydrocyclopenta[b]pyrazine 5-Methyl Furfural Methyl Furoate Methyl Hexanoate Methyl Isovalerate 5-Methyl 2-Phenyl 2-Hexenal Methyl Thiobutyrate Methyl Valerate P-Naphthyl Ethyl Ether Phenyl Ethyl Cinnamate Phenyl Ethyl Propionate Propyl Formate Propyl Mercaptan Salicylaldehyde 8-T etradecalactone 2-Tridecanone... [Pg.1028]

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