Sakurai

Sakurai J J 1985 Modern Quantum Mechanics (Menlo Park Benjamin-Cummings)... 

Coheii-Taiiiiouji C, Diu B and Laloe F 1997 QuantumMechanics (New York Wiley) Sakurai JJ 19 5 Modern QuantumMechanics Park Beiijamiii-Cuimiiiiigs)... 

Sakurai J J 1994 Modern Quantum Mechanics revised edn (Reading, MA Addison-Wesley)... 

Ogura K, Tsu]igo M, Sakurai K and Yano J 1993 Eiectrochemicai coioration of stainiess steei and the scanning tunneiiing microscopic study J. Electrochem. See. 140 1311... 

Sakurai M, Tada FI, Saiki K, Koma A, Funasaka FI and Kishimoto Y 1993 Epitaxial growth of Cgg and Cyq films... 

Flashizume T, Motai K, Wang X D, Shinohara FI, Salto Y, Maruyama Y, Ohno K, Kawazoe Y, Nishina Y, Pickering FI W, Kuk Y and Sakurai T 1993 Intramolecular structures of Cgq molecules adsorbed on the Cu(111) surface Rhys. Rev. Lett. 71 2959-62... 

Conventional synthetic schemes to produce 1,6-disubstituted products, e.g. reaction of a - with d -synthons, are largely unsuccessful. An exception is the following reaction, which provides a useful alternative when Michael type additions fail, e. g., at angular or other tertiary carbon atoms. In such cases the addition of allylsilanes catalyzed by titanium tetrachloride, the Sakurai reaction, is most appropriate (A. Hosomi, 1977). Isomerization of the double bond with bis(benzonitrile-N)dichloropalladium gives the y-double bond in excellent yield. Subsequent ozonolysis provides a pathway to 1,4-dicarbonyl compounds. Thus 1,6-, 1,5- and 1,4-difunctional compounds are accessible by this reaction. 

K. Okumura and V Sakurai, Shukuryo Kenkyusho Kenkvu Koknku. 12. 81 G957i Ciicm. Absir., 58. 5674. 

---