Sakurai reaction Titanium chloride

Lithium diallylcuprate, 11 Lithium dibutylcuprate, 61 Lithium dimethylcuprate, 63, 258 Sakurai reaction Alkylaluminum halides, 5 Allyltrimethylsilane, 11, 305 Titanium(IV) chloride, 304 with other organometallic agents (IS, 2S) -2-Amino-3-methoxy-1 -pheny 1-1-propanol, 17... [Pg.361]

SAKURAI REACTION Alkylaluminum halides. Titanium(IV) chloride... [Pg.663]

Almost 15 years ago Sakurai and Hosomi, in pioneering work, showed that intermolecular addition of an allylsilane to a,j6-unsaturated ketones in the presence of titanium(IV) chloride as the Lewis acid gave the desired 1,4-addition products1 4. In the case of 4,4a,5,6,7,8-hexahy-dro-2(3//)-naphthalenone, reaction was shown to proceed by 1,4-addition with exclusive production of the ris-fused product in high chemical yield. [Pg.937]

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