Ruthenocenyl complexes

Figure 1.6 Selected ferrocenyl and ruthenocenyl complexes are perfectly aligned and, thus, to large SHG efficiency in the solid...

Molecular Second-Order NLO Results as p Product for Ferrocenyl and Ruthenocenyl Complexes... 

The binuclear iron complexes (317) have been found to undergo a thermal rearrangement to afford the complexes (318), which were evidently formed via a metathesis between Si—Si and Fe—Fe bonds in (317). A similar rearrangement has been observed in a disilyl-bridged bis(cyclopentadienyl)tetracarbonyldiruthenium complex. Unprecedented and stable in — rf J7 -pentafulvadiene)dimthenium complexes (320) have been prepared" from a two-electron oxidation of frani -l,2-bis(mthenocenyl)ethylenes (319), and dimethyl analogues have been similarly obtained from trans- and cM-l,2-dimethyl-l,2-bis(ruthenocenyl)ethylenes. 

Bis(ruthenocenyl)allylium cation, characterization, 6, 644 Bis(silylamido) amines, with Zr(IV), 4, 790 Bis(silylamido) complexes, with Zr(IV), 4, 767 Bis-silylation... 

Other heterobimetallic aryl-phosphine-gold(I) complexes with different ferrocenyl derivatives, such as A-[2-A/,A/-(dimethylaminoethyl)-A-methyl-aminoethyl]-ferrocenyl (FcN,N), 2-nitroferrocenyl or ruthenocenyl, have also been reported. 

RUTHENOCENYL DERIVATIVES AND OTHER COMPLEXES OF r/ -CYCLOPENTADIENYL AND RELATED LIGANDS... 

A Pt complex with aryl and ruthenocenylethynyl ligands 792 has been prepared, and its oxidation by AgBp4 results in aryl(ruthenocenyl)acetylene (Equation (152)). Oxidation occurs at the Ru center to form ruthenocenium, but electron transfer between Pt and Ru causes partial formation of the cationic Pt(iii) species which shows rapid reductive elimination of the two organic ligands. 

---