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RUTHENIUM PENTAFLUORIDE

Formation of the adduct chlorine trifluoride-ruthenium pentafluoride by reaction... [Pg.1344]

Formation of the adduct chlorine trifluoride—ruthenium pentafluoride by reaction with ruthenium metal at ambient temperature is extremely violent. [Pg.1388]

Although the third structure type was established for ruthenium pentafluoride (88), the results were based on restricted single-crystal data, giving less accurate molecular dimensions. Full data were used for the structure analysis of the osmium compound (89 ) but the results were still unsatisfactory, because of the predominant scattering by the... [Pg.103]

J A recent paper by Holloway and Knowles, clarifies the earlier work of Edwards, Holloway, and Peacock and extends it to ruthenium pentafluoride and osmium pentafiuoride complexes. Where there is overlap between the work described in Holloway and Knowles paper with the work described in this paper, there is substantial agreement. [Pg.96]

Table 2 gives some of the physical properties of the known pentafluorides. Iridium pentafluoride is isomorphous and nearly isodimensional with ruthenium pentafluoride and presumably has the nonlinear fluorine-bridged tetrameric molecular structure, reported by Holloway, Peacock, and Small for that fluoride. In this arrangement the... [Pg.272]

Rhodium pentafluoride is isomorphous with its ruthenium, osmium, and iridium analogues, the crystal data being a, 12-28 b, 9-86 c, 6-48 A ]3, 99-2° Uobs-, 654-2 A Z = 8. Presumably the structural unit of this compound is a fluorine-bridged tetramer, as in ruthenium pentafluoride. It is noteworthy that the unit-cell volume is smaller than in the ruthenium analogue, possibly as a... [Pg.273]

W. J. Casteel, Jr., A. P. Wilkinson, H. Borrmann, R. E. Serfass and N. Bartlett, Preparation and Structure of Ruthenimn Tetrafluoride and a Structural Comparison with Ruthenium Trifluoride and Ruthenium Pentafluoride, Inorg. Chem. 31 (1992) 3124-3131. [Pg.608]

RuF5 RUTHENIUM PENTAFLUORIDE 253.0895 -1.0396E+04 -9.8031E+01 8.5375E-02 -3.0601E... [Pg.355]

RuF5 RUTHENIUM PENTAFLUORIDE 1399 Sb203[0] DIANTIMONY TRIOXIDE (ORTHORHOMBIC) 1444... [Pg.1916]

See other pages where RUTHENIUM PENTAFLUORIDE is mentioned: [Pg.206]    [Pg.224]    [Pg.101]    [Pg.83]    [Pg.355]    [Pg.361]    [Pg.58]    [Pg.97]    [Pg.203]    [Pg.208]    [Pg.40]    [Pg.361]    [Pg.248]    [Pg.354]    [Pg.360]    [Pg.248]    [Pg.354]    [Pg.360]    [Pg.1399]    [Pg.485]    [Pg.248]    [Pg.354]    [Pg.360]    [Pg.364]    [Pg.367]   
See also in sourсe #XX -- [ Pg.248 ]

See also in sourсe #XX -- [ Pg.248 ]

See also in sourсe #XX -- [ Pg.673 ]

See also in sourсe #XX -- [ Pg.776 ]



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