Ruthenium miscellaneous reactions

Oxidation reactions (Continued) Miscellaneous reactions f-Butyl hydroperoxide-Dichlorotris-(triphenylphosphine)ruthenium(II), 54... [Pg.370]

In terms of miscellaneous reactions associated with aziridine synthesis, a ruthenium porphyrin catalyst was reported to facilitate a unique three-component coupling of nitroarenes with alkynes and a-diazo compounds to produce multifunctional aziridines (14OL1048). Pictured below is an intriguing palladium-catalyzed C-H bond activation/amination leading to the selective transformation of an aminolactone methyl group adjacent to an unprotected secondary amine into an aziridine (14NAT129). [Pg.74]

The 13 chapters of this book survey a range of fields of organic syntheses promoted by ruthenium catalysts, which involve hydrogenation, oxidation, various carbon-carbon bond formations, C-H activation, carbonylation, isomerization, bond-cleavage reaction, metathesis reaction, and miscellaneous nucleophilic and electrophilic reactions. [Pg.2]

Ruthenium clusters containing oxygenated diphosphine ligands Triruthenium and triosmium clusters obtained through orthometallation reactions Triruthenium complexes isolated during catalytic experiments Addition of phosphorus ligands to cationic triosmium complexes Miscellaneous oomplexes... [Pg.835]