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ROBINSON-ALLAN-KOSTANECKI Chromone

ROBINSON - ALLAN - KOSTANECKI Chromone Synthesis Synthesis of chromones or coumannes from o acyioxy aromatic ketones... [Pg.321]

The conversion of c>-hydroxyaryl ketones la to chromones 2a and/or coumarins 3a with aliphatic acid anhydrides in the presence of the sodium or potassium salt of the corresponding acid and the reaction between lb and aromatic acid anhydrides and the salt of the corresponding acid to form flavones 2b (Allan-Robinson) is called the Kostanecki-Robinson (K-R) reaction. ... [Pg.521]

Although the literature refers to the formation of chromones/coumarins as the Kostanecki reaction (and often the Kostanecki-Robinson reaction) and the synthesis of flavones as the Allan-Robinson reaction, others have chosen to merge the two reactions and refer to both transformations as the Kostanecki-Robinson reaction. This section will follow the latter school of thought, and use the Kostanecki-Robinson (K-R) nomenclature. [Pg.522]


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ROBINSON-ALLAN-KOSTANECKI Chromone Synthesis

Robinson

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