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Reynolds number current distribution

Available experimental results on temperature distribution in plugged SA were analyzed to determine the main characteristics of velocity and temperature profiles of singlephase flow, namely recirculation zone length, coolant flow distribution in SA, coolant temperature rise in the wake, etc. At the same time, it is clear that data currently available provide only rough estimations of SA thermohydraulic characteristics in case of blockage as a function of Reynolds number and blocked flow area. [Pg.44]

Fig. 2.13 Current versus overpotential curves showing the effect of experimental parameters in the presence of forced convection, according to the relationship = /cL lnFc. (a) Electrode size (and shape). Ideally, in the presence of a uniform current-density distribution, Deviations may be due to edge effects, non-uniformity of flow (e.g. entrance length effects) or contributions from natural convection, (b) Concentration of electroactive species in the reactor. ii should be proportional to c. It is sometimes convenient to test this by incremental increases in c . The background curve is represented by = 0. (c) Relative velocity of the electrolyte or electrode, cc where x is a constant which depends upon the geometry and flow conditions, x may vary slightly over different ranges of Reynolds number. The limiting-current plateau may shorten and tilt as velocity increases, due to the increasing importance of electron transfer to the overall reaction kinetics. The maximum on the 1 curve may arise due to unsteady-state mass transport and is akin to a peak in linear sweep voltammetry, i.e. it may arise due to an excessive rate of potential change. Fig. 2.13 Current versus overpotential curves showing the effect of experimental parameters in the presence of forced convection, according to the relationship = /cL lnFc. (a) Electrode size (and shape). Ideally, in the presence of a uniform current-density distribution, Deviations may be due to edge effects, non-uniformity of flow (e.g. entrance length effects) or contributions from natural convection, (b) Concentration of electroactive species in the reactor. ii should be proportional to c. It is sometimes convenient to test this by incremental increases in c . The background curve is represented by = 0. (c) Relative velocity of the electrolyte or electrode, cc where x is a constant which depends upon the geometry and flow conditions, x may vary slightly over different ranges of Reynolds number. The limiting-current plateau may shorten and tilt as velocity increases, due to the increasing importance of electron transfer to the overall reaction kinetics. The maximum on the 1 curve may arise due to unsteady-state mass transport and is akin to a peak in linear sweep voltammetry, i.e. it may arise due to an excessive rate of potential change.

See other pages where Reynolds number current distribution is mentioned: [Pg.262]    [Pg.200]    [Pg.166]    [Pg.168]    [Pg.175]    [Pg.307]    [Pg.312]    [Pg.262]    [Pg.673]    [Pg.3090]    [Pg.373]    [Pg.1899]    [Pg.383]    [Pg.942]   
See also in sourсe #XX -- [ Pg.190 ]




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