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Reversible addition-fragmentation organic

Organic chemists have been aware of reversible addition-fragmentation involving xanthate esters in organic chemistry for some time. It is the basis of the Barton-McCombie process for deoxygenation of alcohols (Scheme 9.37).402 404... [Pg.502]

In 1988 a paper by Zard and coworkers4(, reported that xanlhates were a convenient source of alkyl radicals by reversible addition-fragmentation and used the chemistry for the synthesis of a monoadduct to monomer (a maleimide). Many applications of the chemistry in organic synthesis have now been described in papers and reviews by the Zard group.406 407... [Pg.503]

And not only for organic synthesis the reversible addition fragmentation to the thiocarbonylthio motif found in xanthates, dithiocarbamates, dithioesters, trithiocarbonates etc., discussed in Scheme 2 for the particular case of xanthates, is now being actively exploited for the synthesis of bloc polymers. For a recent review, see [75] for the original patents on MADIX and RAFT, see [76,77]. The principle of this approach is summarised in Scheme 38 for the synthesis of a diblock polymer 66. The RAFT and MADIX processes, as they are now called, are set to revolutionise the crafting of polymers with well-defined architectures. It is an extremely effective technique that can be applied to essentially all commercial monomers and is tolerant of many functional groups. Scientific papers and patents on the subject now number in the hundreds. [Pg.233]

Lowe AB, McCormick CL (2007) Reversible addition-fragmentation chain transfer (RAFT) radical polymerization and the synthesis of water-soluble (co)polymers under homogeneous conditions in organic and aqueous media. Prog Polym Sci 32 283-351... [Pg.47]

Reversible Addition-Fragmentation Chain Transfer. The RAFT represents a process for performing living free radical polymerization. Many simple organic compounds possessing a thiocarbonylthio (S=C—S) moiety are employed... [Pg.6931]


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See also in sourсe #XX -- [ Pg.93 ]




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Addition reverse

Addition reversible

Addition-fragmentation

Fragmentation additivity

Organic addition

Organic additives

Reverse additives

Reversible addition-fragment

Reversible addition-fragmentation

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