Restrictive primitive model

Orkoulas G and Panagiotopoulos A Z 1999 Phase behavior of the restricted primitive model and square-well fluids from Monte Carlo simulations in the grand canonical ensemble J. Chem. Phys. 110 1581... 

Rasaiah J C, Card D N and Valleau J 1972 Calculations on the restricted primitive model for 1-1-electrolyte solutions J. Chem. Phys. 56 248... 

Gillan M 1980 Upper bound on the free energy of the restricted primitive model for ionic liquids Mol. Phys. 41 75... 

Using the Omstein-Zemicke equation, numerical solutions for the restricted primitive model can be. 

The popular and well-studied primitive model is a degenerate case of the SPM with = 0, shown schematically in Figure (c). The restricted primitive model (RPM) refers to the case when the ions are of equal diameter. This model can realistically represent the packing of a molten salt in which no solvent is present. For an aqueous electrolyte, the primitive model does not treat the solvent molecules exphcitly and the number density of the electrolyte is umealistically low. For modeling nano-surface interactions, short-range interactions are important and the primitive model is expected not to give adequate account of confinement effects. For its simphcity, however, many theories [18-22] and simulation studies [23-25] have been made based on the primitive model for the bulk electrolyte. Ap-phcations to electrolyte interfaces have also been widely reported [26-30]. 

Yan, Q.L. de Pablo, J.J., Hyper-parallel tempering Monte Carlo Application to the Lennard-Jones fluid and the restricted primitive model, J. Chem. Phys. 1999, 111, 9509-9516... 

Carlo Application to the Lennard-Jones Fluid and the Restricted Primitive Model. 

V. RESULTS FROM MEAN-FIELD THEORIES A. The Restricted Primitive Model... 

---