Resistive-capacitive semi-infinite transmission

Fig. IL5.4 Resistive-capacitive semi-infinite transmission line infinite diffusion. R and C are normalized to unit length...

Fig. 11.17. A resistive-capacitive transmission line that describes a semi-infinite...

Equation (IL5.36) shows that the Warburg impedance cannot be represented as a series combination of frequency-independent elements in an equivalent circuit. This is possible, however, by a semi-infinite resistive-capacitive transmission line with a series resistance R per unit length and a shunt capacity C per unit length (Fig. IL5.4). 

The impedance of a porous electrode can be simulated with the transmission line model, and the penetration depth can be evaluated [24]. For the non-porous Pt-modified as-deposited surface, the methanol oxidation reaction can be simulated as a simple Randles equivalent circuit comprising a parallel combination of a double layer capacitance and a semi-infinite Warburg impedance in series with a charge transfer resistance. 

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