Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Reflux effect

Reduction of arenes.1 Raney nickel (Mozingo type) in combination with 2-propanol (reflux) effects reduction of aromatic rings in 2-18 hours. Naphthalene is reduced in 18 hours to tetralin (90% yield) and cis- and frans-decalin (10% yield). Anisole is reduced in 110 hours to cyclohexyl methyl ether (90% yield). Nitrobenzene is reduced quickly to aniline and then further to cyclohexylamine and cyclohexylisopropylamine. [Pg.266]

The Smuda process uses a reflux return where longer paraffin chains that condense shortly after exiting the main chamber are allowed to flow back to the main chamber (the reflux effect ). Also the heavies from the bottom of the distillation column flow back to the pyrolysis chamber for re-cracking (Figure 15.10b). [Pg.417]

We start the chapter by explaining the graphical thermodynamic representations for ternary mixtures known as Residue Curve Maps. The next section deals with the separation of homogeneous azeotropes, where the existence of a distillation boundary is a serious obstacle to separation. Therefore, the choice of the entrainer is essential. We discuss some design issues, as entrainer ratio, optimum energy requirements and finite reflux effects. The following subchapter treats the heterogeneous azeotropic distillation, where liquid-liquid split is a powerful method to overcome the constraint of a distillation boundary. Finally, we will present the combination of distillation with other separation techniques, as extraction or membranes. [Pg.352]

These metal-alkynyl complexes can be protonated to afford the free alkynes and parent cobalt hydroxo complex (comparable reactivity to their alkyl and aryl congeners), but have proven inert toward oxygenation and carbonylation. They are also thermally stable up to 100 °C. Attempts to explore the reactions of these compounds with unsaturated hydrocarbons were typically fruitless. The one exception is the reaction between 53 and its parent alkyne (HC = C02Me, Scheme 6), which under benzene reflux effects catalytic, stereospecific, linear trimerisation of the alkyne to afford ( , )-buta-l,3-dien-5-yne. The reaction was, however, slow (4.5 turnovers in 20 h) and suffered from catalytic deactivation due to hydrolysis of 53, which subsequently reacted with adventitious CO2 to irreversibly form an inert /x-carbonato complex. The catalytic cycle was concluded to involve initially a double coordination-insertion of the C = C bond of methylpropiolate into the Co-Caikyne linkage. Subsequent hydrolysis of the Co-C bond by a third equivalent of HC = CC02Me would then afford the observed product and regenerate 53. However, a definitive explanation for the stereospecificity of the process was not established. [Pg.209]

This is also a commonly encountered control scheme. Both level controls may be calculated by the method of Chapter 16 care should be taken to include the subcooled reflux effect on overhead level control. [Pg.161]


See other pages where Reflux effect is mentioned: [Pg.172]    [Pg.274]    [Pg.230]    [Pg.415]    [Pg.227]    [Pg.308]    [Pg.333]    [Pg.3386]    [Pg.203]    [Pg.204]    [Pg.173]    [Pg.174]   
See also in sourсe #XX -- [ Pg.10 , Pg.11 ]




SEARCH



© 2024 chempedia.info