Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Reductive coupling lithium

Oxalamidinate anions represent the most simple type of bis(amidinate) ligands in which two amidinate units are directly connected via a central C-C bond. Oxalamidinate complexes of d-transition metals have recently received increasing attention for their efficient catalytic activity in olefin polymerization reactions. Almost all the oxalamidinate ligands have been synthesized by deprotonation of the corresponding oxalic amidines [pathway (a) in Scheme 190]. More recently, it was found that carbodiimides, RN = C=NR, can be reductively coupled with metallic lithium into the oxalamidinate dianions [(RN)2C-C(NR)2] [route (c)J which are clearly useful for the preparation of dinuclear oxalamidinate complexes. The lithium complex obtained this way from N,N -di(p-tolyl)carbodiimide was crystallized from pyridine/pentane and... [Pg.307]

Attempts to form cyclotrigermanes (and, subsequently, digermenes see Section II.B.l) from the reductive cyclization of diaryldichlorogermanes and lithium naphthalenide (LiNp) with particularly bulky substituents on the aryl groups (i.e., isopropyl) led, instead, directly to the tetraaryldiger-menes by reductive coupling. [Pg.290]

Attempts to follow a published procedure for the preparation of 1,3 -dithiole-2-thione-4,5-dithiolate salts [1], involving reductive coupling of carbon disulfide with alkali metals, have led to violent explosions with potassium metal, but not with sodium [2], However, mixtures of carbon disulfide with potassium-sodium alloy, potassium, sodium, or lithium are capable of detonation by shock, though not by heating. The explosive power decreases in the order given above, and the first mixture is more shock-sensitive than mercury fulminate [3],... [Pg.223]

Strained cyclotrisilane derivatives, which are silicon analogues of cyclopropane, are prepared by the reductive coupling of overcrowded dichlorodiarylsilanes using lithium naphthalenide (Scheme 14.9). [Pg.656]

REDUCTIVE COUPLING Titanium(III) chloride-Lithium aluminum hydride. [Pg.470]

The reductive coupling of phenacyl bromides using nickel carbonyl (68CC33) or an electrolytic procedure (81S625) provides excellent yields of 2,4-diarylfurans. Coupling of a-bromoaldimines with sodium or lithium provides mainly 3,4-disubstituted pyrroles, whereas isopropylmagnesium bromide yields mainly 2,4-disubstituted pyrroles (Scheme 77)... [Pg.132]

Reductive coupling of carbonyl groups Titanium(IV) chloride-Zinc, 310 From three-membered heterocycles Arylselenocarboxamides, 22 Titanium(IV) chloride-Lithium aluminum hydride, 310... [Pg.382]

Tb(Mes)Si=Si(Mes)Tb (Mes = mesityl) by reductive coupling of Tb(Mes)SiBr2 with lithium naphthalenide262. [Pg.487]

Tetrasilapentanes 4, R = Pr or neo-pentyl, were synthesized by reductive coupling of the linear 1,5-dichloro-l,2,4,5-tetrasilapentane with lithium biphenyl in 77-87% yields <2002EJI1772>. [Pg.665]

Reductive coupling of iodonium salts catalysed by a palladium-zinc system also produced biaryls in good yield [38]. Also very effective was the palladium-catalysed cross-coupling of iodonium salts with sodium tetraphenylborate in water [39]. The reaction of 3-indolyl phenyliodonium trifluoroacetate with several alkyl and aryl lithium reagents gave 3-substituted indoles [40] ... [Pg.141]

The complex formed on addition of cuprous iodide to a solution of a lithium dialkylamide in ether or tetrahydrofuran is effective in the reductive coupling of allylic halides to give 1,5-dienes with preservation of stereochemistry. This method has been used5 for the stereospecific synthesis of all-trans-squalene and (E,Z,Z,E) squalene from (E,E)- and (Z,JE)-farnesyl bromides, respectively. In an attempted synthesis of (3S)-squalene-2,3-epoxide, 4-[(4R)-2,2,5,5-tetramethyl-l,3-dioxolan-4-yl]butan-2-one (1) and the phosphonium iodide (2) were prepared.6 Unfortu-... [Pg.118]


See other pages where Reductive coupling lithium is mentioned: [Pg.132]    [Pg.933]    [Pg.35]    [Pg.194]    [Pg.933]    [Pg.1213]    [Pg.23]    [Pg.547]    [Pg.214]    [Pg.403]    [Pg.438]    [Pg.45]    [Pg.70]    [Pg.301]    [Pg.885]    [Pg.44]    [Pg.159]    [Pg.159]    [Pg.161]    [Pg.162]    [Pg.228]    [Pg.98]    [Pg.664]    [Pg.309]    [Pg.204]    [Pg.129]    [Pg.579]    [Pg.956]    [Pg.171]    [Pg.146]    [Pg.59]    [Pg.1271]   
See also in sourсe #XX -- [ Pg.273 ]




SEARCH



Lithium reductions

Reduction Reductive coupling

Reduction couple

© 2024 chempedia.info