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Redistribution benzene

Rate law and mechanism. The redistribution of alkyl groups on silanes in benzene is catalyzed by aluminum bromide. Suggest a scheme for it on the basis of the rate equation given. [Pg.149]

Isomerization and transalkylation reactions to redistribute methyl groups on aromatic molecules are important processes in the production of benzene, toluene and xylenes (BTX). In particular, the production of para-xylene is preferred. The interconversion of C8 aromatics is covered in much greater depth in Section 14.3. [Pg.369]

To indicate resonance forms, we use a doubleheaded arrow between the contributing structures. This arrow is reserved for resonance structures and never used elsewhere. The difference between the two structures is that the electrons in the n bonds have been redistributed, and we can illustrate this by use of another type of arrow, a curly arrow. This arrow is used throughout chemistry to represent the movement of two electrons. In the benzene case, a cyclic movement of electrons accounts for the apparent relocation of double bonds, though there are two ways we might show this process both are equally satisfactory. [Pg.46]

Some indication of randomization was seen when the polymers were heated under reflux in benzene for 30 days and then precipitated with methanol. The NMR spectrum showed a slightly broadened methyl signal and small peaks at 8 6.20 and 6.51 ppm, characteristics of random copolymers. The largest peaks by far were those corresponding to the homopolymers redistribution apparently was not extensive enough to affect greatly the structure of the polymer chains. [Pg.259]

Benzene, ethylene and acetylene were the predominate observed volatiles at 550 °C whilst methane was evolved from 650 °C to 875 °C. An amorphous SiCO material was obtained at 1200 °C and bond redistribution and carbothermic reduction occurred up to 1800 °C to give a ceramic material composed of substantial amounts of crystalline fi-silicon carbide. The preparation of bulk ceramic components from materials in the system... [Pg.2232]

These, to some extent, are related to redistribution reactions but, of course, do not lie within the scope of this review. Probably one of the first redistribution reactions of ir-bonded compounds is the exchange of carbonyl groups with 7r-bonded benzene (85) on chromium leading to the mixed compound, benzenechromium tricarbonyl. [Pg.262]

Iwaki LK, Deak JC, Rhea ST, Dlott DD. Vibrational energy redistribution in liquid benzene. Chem Phys Lett 1999 303 176-182. [Pg.598]

To summarize deformed benzene and perfluorobenzene represent two clear-cut cases which underline the importance of rehybridizaton in annelated systems. They also convincingly show that reorganization of the 7r-electron density can be triggered by redistribution of the CC s-characters which takes place in the a-plane, although it is addmitedly true that a part of lengthening of the ipso bonds is due to repulsion between a pairs of two close vicinal H or F atoms. [Pg.56]


See other pages where Redistribution benzene is mentioned: [Pg.40]    [Pg.122]    [Pg.208]    [Pg.141]    [Pg.144]    [Pg.152]    [Pg.587]    [Pg.218]    [Pg.911]    [Pg.287]    [Pg.199]    [Pg.105]    [Pg.65]    [Pg.124]    [Pg.271]    [Pg.272]    [Pg.273]    [Pg.337]    [Pg.443]    [Pg.150]    [Pg.28]    [Pg.357]    [Pg.198]    [Pg.218]    [Pg.102]    [Pg.106]    [Pg.6]    [Pg.151]    [Pg.33]    [Pg.833]    [Pg.24]    [Pg.452]    [Pg.182]    [Pg.234]    [Pg.84]    [Pg.554]    [Pg.587]    [Pg.270]    [Pg.54]    [Pg.82]    [Pg.83]    [Pg.93]    [Pg.96]   
See also in sourсe #XX -- [ Pg.126 ]




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