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Photo-rearrangements

Photo-Fries rearrangement-. Photo-Fries rearrangement involve migra-fSi of a group across a double bond (1,3 migration) in structures of the Plowing type ... [Pg.231]

W. M. Gelbart and S. A. Rice, Some Formal Results in a Theory of Molecular Rearrangements Photo-Isomerism, in J. Chem. Phys. (in press). [Pg.303]

Sonawane, H. R., Bellur, N. S., Kulkarni, D. G., Ahuja, J. R. Photoinduced vinylcyclopropane-cyclopentene rearrangement (photo-VCP-CP) a methodology for chiral bicyclo[3.2.0]heptenes and their application in natural product syntheses. Syn/eff 1993, 875-884. [Pg.700]

The Woodward-Hoffmann concept for concerted electrocyclic reactions guided Childs and Winstein to conclude that benzenium ions should rearrange photo-chemically to bicycloI3.1.0]hexenyl cations When they irradiated so-... [Pg.211]

Photolytic decomposition of polycarbonate films was shown to produce products that are also consistent with the photo-Fries reaction. These are salicylic acid and bisphenol type species [580]. This is in agreement with earlier studies that showed that a variety of processes, including rearrangements (photo-Fries) and photo-oxidation, can occur when bisphenol A-based polycarbonate is photolyzed [581, 582]. [Pg.674]

A large variety of organic oxidations, reductions, and rearrangements show photocatalysis at interfaces, usually of a semiconductor. The subject has been reviewed [326,327] some specific examples are the photo-Kolbe reaction (decarboxylation of acetic acid) using Pt supported on anatase [328], the pho-... [Pg.738]

Beckmann rearrangement, 4, 292 pyrolysis, 4, 202 synthesis, 4, 223 Wittig reaction, 4, 294 Wolff-Kishner reduction, 4, 291 Indole, 1-acyl-2,3-disubstituted photoisomerization, 4, 204 photo-Fries rearrangement, 4, 204 photoisomerization, 4, 42 synthesis, 4, 82 Indole, 2-acyl acidity, 4, 297 synthesis, 4, 337, 360 Indole, 3-acyl-acidity, 4, 297 cleavage, 4, 289 reduction, 4, 289 synthesis, 4, 360 Indole, 7-acyl-synthesis, 4, 246... [Pg.666]

Triazole, 5-amino-1,4-diphenyl-photo-Dimroth rearrangement, 5, 697... [Pg.906]

Acyl azides can undergo photolytic cleavage and rearrangement upon irradiation at room temperature or below. In that case acyl nitrenes 8 have been identified by trapping reactions and might be reactive intermediates in the photo Curtius rearrangement. However there is also evidence that the formation of isocyanates upon irradiation proceeds by a concerted reaction as in the case of the thermal procedure, and that the acyl nitrenes are formed by an alternative and competing pathway " ... [Pg.73]

A photochemical variant, the so-called photo-Fries rearrangement, proceeds via intermediate formation of radical species. Upon irradiation the phenyl ester molecules (1) are promoted into an excited state 11. By homolytic bond cleavage the radical-pair 12 is formed that reacts to the semiquinone 13, which in turn tautomerizes to the p-acylphenol 3. The corresponding ort/zo-derivative is formed in an analogous way ... [Pg.128]

A comparison of the electron impact (El) and chemical ionization (Cl-methane) mass spectra of 1//-azepine-1-carboxylates and l-(arylsulfonyl)-l//-azepines reveals that in the El spectra at low temperature the azepines retain their 8 -electron ring structure prior to fragmentation, whereas the Cl spectra are complicated by high temperature thermal decompositions.90 It has been concluded that Cl mass spectrometry is not an efficient technique for studying azepines, and that there is no apparent correlation between the thermal and photo-induced rearrangements of 1//-azepines and their mass spectral behavior. [Pg.114]

A variant of Method B is the cyclization of the phenolic 2-(chloroacetamido)benzophenones 9, produced by photo-Fries rearrangement (see Houben-Weyl, Vol. 7/2a, p 1148 ff) of the esters 8, with ammonia via the corresponding iodoacetyl compounds.195... [Pg.392]


See other pages where Photo-rearrangements is mentioned: [Pg.260]    [Pg.412]    [Pg.576]    [Pg.412]    [Pg.260]    [Pg.208]    [Pg.650]    [Pg.165]    [Pg.143]    [Pg.260]    [Pg.412]    [Pg.576]    [Pg.412]    [Pg.260]    [Pg.208]    [Pg.650]    [Pg.165]    [Pg.143]    [Pg.2948]    [Pg.757]    [Pg.392]    [Pg.59]    [Pg.269]    [Pg.138]    [Pg.142]    [Pg.539]    [Pg.574]    [Pg.656]    [Pg.732]    [Pg.253]    [Pg.313]    [Pg.210]    [Pg.17]    [Pg.291]    [Pg.286]    [Pg.47]    [Pg.142]    [Pg.726]   
See also in sourсe #XX -- [ Pg.154 , Pg.177 ]

See also in sourсe #XX -- [ Pg.329 , Pg.330 ]




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2.4- Cyclohexadienones photo rearrangements

Amides photo-Fries rearrangement

Arbuzov photo-rearrangement

Cope rearrangement photo-stimulated electrontransfer

Esters photo-Fries rearrangement

Fries rearrangement photo

Light photo-Fries rearrangement

Moieties photo-Fries rearrangement

Phenyl acetate Fries rearrangement photo

Photo Curtius rearrangement

Photo-Beckmann rearrangement

Photo-Beckmann rearrangement oxaziridine intermediate

Photo-Claisen rearrangements

Photo-Cope rearrangement

Photo-Favorskii Rearrangement

Photo-Fries rearrangement 1-naphthyl acetate

Photo-Fries rearrangement 1-naphthyl esters

Photo-Fries rearrangement aryl ester

Photo-Fries rearrangement cyclodextrins

Photo-Fries rearrangement disubstituted

Photo-Fries rearrangement lactone

Photo-Fries rearrangement poly

Photo-Fries rearrangement polymers

Photo-Fries rearrangement products, formation

Photo-Fries rearrangement xanthones

Photo-Fries rearrangement zeolites

Photo-Fries rearrangement, phenyl esters

Photo-Fries-type rearrangement

Photo-Friess rearrangement

Photo-Smiles rearrangement

Photo-Wagner-Meerwein rearrangement

Photo-Wolff rearrangement

Photochemical reactions reaction Photo-Fries rearrangement

Photochemistry photo Fries rearrangement

Poly photo-rearrangement

Polycarbonates photo-rearrangement

Rearrangements photo-Fries rearrangement

Rearrangements photo-induced

Schmidt rearrangement photo

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