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Reactivity-Based One-Pot Glycosylation Fine-Tuning of Anomeric Reactivities

1 Reactivity-Based One-Pot Glycosylation Fine-Tuning of Anomeric Reactivities [Pg.156]

SCHEME 6.1 General scheme for reactivity-based one-pot glycosylation. [Pg.156]

Analogously, Hirosato Kondo and coworkers carried out the one-pot assembly of Lewis X derivatives by taking advantage of the electronic disarming effect [Pg.157]

SCHEME 6.3 Yu s synthesis of tricolorin A. DDQ, 2,3-dichloro-5,6-dicyano-l-4,-benzoquinone. [Pg.158]

To synthesize longer oligosaccharide sequences using the armed-disarmed one-pot glycosylation approach, more than two consecutive glycosylation reactions are often [Pg.158]




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Anomeric glycosylation

Fine tuning

One-pot glycosylation

Reactive base

Tuning

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